TiO2纳米管.pptVIP

Enhanced Photovoltaic Performance of Nanostructured Hybrid Solar Cell Using HighlyOriented TiO2 Nanotubes Supan Yodyingyong, Xiaoyuan Zhou, Qifeng Zhang, Darapond Triampo, Junting Xi, Kwangsuk Park, Benjie Limketkai, and Guozhong Cao 2010 American Chemical Society A lot of effort is being made to develop so-called third generation of solar cells including dye-sensitized solar cells, DSCs ,and organic photovoltaics, OPVs. OPVs or polymer-based photovoltaic devices can be processed from solution and have become a promising low cost alternative to traditional inorganic solar cell. The key of the polymer solar cells is the bulk heterojunction, which is a blend of electron-donating semiconducting polymers and electron-withdrawing fullerides. This bulk heterojunction morphology enhances the interfacial area, where the photogenerated excitons, electron hole pairs, are dissociated into charge carriers, and enables holes and electrons to be transported and collected. The power conversion ef?ciency (PCE) of the bulk heterojunction polymer solar cells which certi?ed by the National Renewable Energy Laboratory (NREL) of up to 8.13% have been recently reported by Solarmer Energy. However, polymer-based solar cells still suffer from low ef?ciencies and the limited lifetime as compared to silicon-based solar cell. The limited ef?ciency of the bulk heterojunction polymer solar cell is due to the lower charge mobility in polymer, the short exciton diffusion length, which can only diffuse around 20 nm, the charge trapping in the conducting pathways of fullerides and polymer to the electrodes, and the mismatch of the absorption spectrum of the active layer and the solar emission. To address the intrinsic limitations of polymer solar cells, new strategies have been investigated such as the development of new polymers with a low bandgap for better match absorption of the solar spectrum, and a hybrid organic/inorganic solar cells (hybrid solar cells). The hybrid solar cells using a v