加压和超临界流体在多孔膜中的渗透.pdfVIP

第 19 卷第 5 期 高 校 化 学 工 程 学 报 No.5 Vol.19 2005 年 10 月 Journal of Chemical Engineering of Chinese Universities Oct. 2005 文章编号 1003-9015(2005)05-0577-06 加压和超临界流体在多孔膜中的渗透 高 翔 1, 刘丽丽 1, 刘秀凤 1, 张宝泉 1, 林跃生 1,2 (1.天津大学 化工学院, 天津 300072; 2.Department of Chemical and Materials Engineering, University of Cincinnati, Cincinnati, Ohio 45221, USA) 摘 要 考察加压和超临界流体在多孔膜中渗透过程的各种影响因素并进行模型分析 对深入认识过程的传质机理 开发普遍适用的数学模型有重要意义 首先实验测定了不同温度 压力和压差条件下 He N2 和 CO2 在多孔陶瓷膜中 的渗透率 考察了各主要影响因素 以二项尘气模型为基础 考虑到流体粘度随压力的变化 特别是近临界区流体粘 度可能出现的突变 对模型进行了修正 建立了新的模型表达式 理论分析与实验结果表明 加压和超临界条件下 由于 He 的粘度变化甚微 其渗透过程仍然符合二项尘气模型 而对于 N2 需要考虑粘度随压力变化对渗透率计算结果 的影响 由于近临界区相变的作用 CO2 在多孔膜中的渗透过程出现奇异现象 而在低压和高压条件下 本研究建立 的渗透模型与实验结果十分吻合 关键词 多孔膜 超临界流体 膜渗透 渗透模型 中图分类号 TQ028.8 文献标识码 A Permeation of Compressed and Supercritical Fluids through Porous Membranes GAO Xiang1, LIU Li-li1, LIU Xiu-feng1, ZHANG Bao-quan1, LIN Y. S.1, 2 (1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; 2. Department of Chemical and Materials Engineering, University of Cincinnati, Cincinnati, Ohio 45221, USA) Abstract: For the permeation of compressed and supercritical fluids through porous membranes, the investigation on major influence factors and process modeling is essential. The permeance of helium, nitrogen and carbon dioxide at various temperature, pressure and pressure difference was measured at first. A new model equation was developed by modifying the two-term dusty-gas model. The variation of viscosity with pressure, especially in the near-critical region where the possible abnormal change of viscosity with pressure may exist, was considered in the model development. The results of experimental measurement and theoretical analyses show that the permeation of helium in porous membrane agrees well with the two-term dusty-gas model due to