改性蒙脱土对除草剂敌草隆的吸附及催化降解行为研究__本科论文.docVIP

改性蒙脱土对除草剂敌草隆的吸附及催化降解行为研究 Study on dsorption and Photocatalytic Degradation of Diuron in Modified Montmorillonite 作 者 姓 名： 叶 小 贝学 位 类 型： 学 历 硕 士学 科、专 业： 市 政 工 程研 究 方 向：城镇给水与排水工程技术导 师 及 职 称： 袁守军副教授 2012年4月CTAB-MMT）对敌草隆的吸附机理，及其影响因素。试验结果表明，吸附作用符合Freundlich等温线方程，反应是自发进行的吸热反应；吸附反应可以用准二级动力学模型进行描述；在一定范围内，离子强度对敌草隆的吸附略有抑制作用；腐殖酸在一定程度上促进蒙脱土对敌草隆的吸附；溶液pH值对吸附过程略有影响，中性条件有利于吸附。除草剂扑草净拥有与敌草隆相近的吸附机理，并且扑草净对改性蒙脱土吸附敌草隆具有协同吸附作用。 (2) 研究了钛柱撑蒙脱土（TiO2-MMT）对敌草隆的光催化降解机理，试验表明，TiO2-MMT用量为1.g/mg敌草隆时，敌草隆光催化降解率最高；溶液pH=2-8时，pH值越高，降解效率越大，pH8时，随着pH值升高，降解效率变化缓慢；TiO2-MMT和双柱撑蒙脱土（CTAB-TiO2-MMT）的降解效果好，而CTAB-MMT和CTAB-TiO2-MMT的吸附效果好，因此，CTAB-TiO2-MMT具有良好的吸附降解性能，并且这种材料对典型除草剂敌草隆和扑草净的催化降解可以用一级动力学模型来描述，半衰期分别为47.47min和54.96min；TiO2-MMT和CTAB-TiO2-MMT均有良好的重复使用性能。Study on adsorption and photocatalytic degradation of Diuron in modified montmorillonite ABSTRACT A variety of pesticides including insecticides and herbicides are widely used to improve crop yields in the agricultural production industry. Only a small fraction of this pesticides can play a direct role in killing insect and weeding on crop.The majority of pesticides is sprayed into the ecological environment with rainoff and atmospheric,and become organic pollutants which threat to humans and animals,resulting in eclolgical risks.In this paper,the herbicide diuron were selected to investigate its behavior of adsorption and photocatalytic degradation on modified montmorillonite in environment.The main comclusions were obtained as follows: Firstly，pseudo-second order kinetics model. Ionic strength inhibit the adsorption of diuron within a certain range. Humic acid could promote the adsorpton of diuron on montmorillonite to a certain extent. The solution of pH have slightly affected on the adsorption process,and it is conducive to adsorption when pH=6 to 8. Herbicide prometryn has a similar adsorption mechanism of diuron,and adsorption of prometryn have synergy with diuron on modified montmorillonit