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2015-TiO2LDH--光催化产氧--Advanced_Functional_Materials
FU
LL P
A
P
ER
? 2015 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim 1
electron–hole pairs generated by unfa-
vorable band structure greatly limits their
practical applications, which is an urgent
problem to be solved as well. [ 9–11 ] There-
fore, to satisfy the requirements of water
splitting, the development of new mate-
rials or methodologies to obtain effi cient
photocatalysts with advantage of extended
light response and an improved electron–
hole separation effi ciency remains a tre-
mendous challenge.
In order to enhance the water split-
ting performance, an effective way is to
build elaborate hybrid semiconductors
with high effi ciency of solar light utili-
zation. [ 12–14 ] Recently, research interest
on the nanostructured semiconduc-
tors is extended to 2D inorganic solids
due to their large surface area and high
photocatalytic effi ciency. [ 15,16 ] Layered
double hydroxides (LDHs) are 2D lay-
ered anionic clays generally expressed as
[M II 1 -x M III x (OH) 2 ](A n? ) x/n · m H 2 O (M II and
M III are divalent and trivalent metals respectively, A n? is inter-
layered anion). [ 17–20 ] Owing to their visible-light-response capa-
bility and large quantum yield, transition-metal-bearing LDH
materials with semiconductor properties have attracted con-
siderable attention as visible-light-induced photocatalysts. [ 21–23 ]
However, pristine LDHs generally suffer from poor control
over particle size, morphology as well as crystalline orientation,
which restricts the effi ciency of charge separation and photo-
conversion capability. [ 24,25 ] Taking into account the fact that TiO 2
nanocrystal can act as a good acceptor for photogenerated elec-
trons, [ 1,5 ] the hybridization of TiO 2 with LDHs would provide
an effective way to enhance the charge separation and photo-
catalytic effi ciency. In this regard, the resulting heterostructure
material would possess the following advantages: (i) prominent
full sunlight utilization will be achieved ow
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