X70钢在模拟潮湿存储环境中的点蚀行为解释.pdfVIP

第 47卷 第 8期 2011年 8月 第 1009-1016页 仓 扁 学 玫 ACTA METALLURGICA SINICA VlO1．47 No．8 Aug． 2011 PP．1009—1016 X70钢在模拟潮湿存储环境中的点蚀行为 刘智勇 ，。) 董超芳 ) 贾志军 ) 李晓刚 ) 1)北京科技大学腐蚀与防护中心腐蚀与防护教育部重点实验室，北京 100083 2)南昌航空大学材料科学与工程学院，南昌330063 摘 要 应用电化学极化技术、电化学阻抗谱、模拟浸泡实验，研究了 X70钢在模拟潮湿存储环境中点蚀的发生机制及规律．结 果表明，X70钢在模拟潮湿存储环境中可以发生点蚀，导致点蚀发生的腐蚀介质来 自于层流冷却水中的腐蚀性物质，其中 HC0 和NO3是致钝剂，而C1一和sol一可破坏钝化膜，促进点蚀发生．在0．5 mol／L的NaHCO3介质中当C1一浓度达到 0．02 mol／L时钝化膜即失去保护性．Cl一浓度是影响点蚀的萌生和发展的关键因素，当其浓度较低时点蚀容易形核，但仅有少数 能够长大；而当其浓度适中(约0．149 mol／L)时点蚀敏感性最高，点蚀容易长大；当其浓度过高时发生均匀腐蚀，点蚀难以长大． 关键词 X70管线钢，点蚀，潮湿存储环境 中图法分类号 TG174．2 文献标识码 A 文章编号 0412—1961(2011)08—1009—08 PITTING CoRR0SIoN oF X7O PIPELINE STEEL IN THE SIM ULATED W ET SToRAGE ENVIRoNM ENT LIU Zhiyong 1,2 DONG Chaofang ．JIA Zhijun ．LI Xiaogang 1 1)Corrosion and Protection Center University of Science and Technology Beijing，Key Laboratory of Corrosion and Protection of Ministry of Education，Beijing 100083 2)School of Material Science and Technology，Nanchang Hangkong University,Nanchang 330063 Correspondent：LI Xiaogang，professor,Tet：(o1oE—mail：lixiaogang99@263．net Supported by NationaZ Naturaf Science Foundation of China No．50901o41 J and China Postdoctoraf Science Foundation No．20100480196) M anuscript received 2011-04—08，in revised form 2011-05-23 ABSTRACT Pitting mechanism and behaviour of X70 pipeline steel in humid storage environ— ments were investigated using electrochemical polarization curves．electrochemical impedance spec． trums fEIS)，immersing corrosion tests and corrosion morphology observation through SEM．It was demonstrated that pitting of X70 pipeline steel occurred in simulated moist storage environments．for which the corrosive substances came from the residual species in laminar cooling water introduced during steel manufacture processes．HCO3 and NO；are passivating agents，C1一and S0 —would destroyed the pasivation layer，which could lead to pitting．In solution with 0．5 mol／L NaHCO3， 0．02 mol／L Cl—Was enough to break the passivation layer．C1一concentration i