材料化学翻译解析.docVIP

Journal of Materials Chemistry A 材料化学杂志  PAPER  View Article Online View Journal | View Issue Synthesis and lithium-storage properties of MnO/ reduced graphene oxide composites derived from graphene oxide plus the transformation of Mn(VI) to Mn(II) by the reducing power of graphene oxide 一氧化锰的合成和锂存储特性减少了氧化石墨烯的复合材料，而后者源于氧化石墨烯以及Mn（VI)转化Mn(II)过程中，通过降低氧化石墨烯能量生出的转化物 In this report, a novel method is proposed to prepare MnO/reduced graphene oxide (rGO) composites via calcining the precursors (i.e. d-MnO2/graphene oxide composites) at 500 C in Ar using no external reducing gas, in which graphene oxide (GO) successfully serves as a reductant by releasing CO during its thermolysis for the first time.By controlling the initial ratios of GO to KMnO4, di?erently composed precursors can be obtained via the redox reaction between GO and KMnO4, then leading to the formation of composites with di?erent MnO/rGO ratios and dispersion of MnO on the rGO surface (denoted as MGC1 and MGC2). When applied as an active material in lithium ion batteries, MGC1 shows excellent cycling performance and capacity retention. Under 100 and 200 mA g -1, MGC1 could deliver reversible capacities as high as 900 and 750 mA h g 1, respectively, after more than 100 cycles. Considering the simple operation and low energy consumption in the whole material synthesis processes, the present strategy is feasible and e?ective for practical application. Even more importantly, the reductibility of graphene oxide upon thermolysis is utilized for the first time, which is meaningful for its extension in synthesis of functional nanomaterials. 在这份报告中，提出了制备一氧化锰/还原氧化石墨烯复合材料的一种新方法，.通过在氩气中，500℃ 的条件下 使用没有外部的还原性气体，煅烧前驱体（i.e .d-二氧化锰/氧化石墨烯复合材料）,在此过程中，氧化石墨烯完全可以胜任还原剂的功能，首次热解，释放一氧化碳..控制氧化石墨烯（GO）和KMnO4的初始比KMnO4，通过氧化石墨烯（GO）和KMnO4氧化还原反应获得不同组成的前体，形成的复合材料具有不同MnO / rGO比率和MnO，rGO表面不同的色散(用MGC1和MGC2表示)。当应用于锂离子电池的活性材料时，MGC1具有优异的循环性能和容量保持率。在100和200 mA g-1下，MGC1可以提供可逆容量高达900和750 mA h g-1 ，分别在10