(SI) Directing Self Assembly of Nanoscopic Cylindrical Diblock Brush Terpolymers into Films with.pdf

Copyright WILEY-VCH Verlag GmbH Co. KGaA, 69469 Weinheim, Germany, 2013. Supporting Information for Macromol. Rapid Commun., DOI: 10.1002/marc.201300845 Directing Self-Assembly of Nanoscopic Cylindrical Diblock Brush Terpolymers into Films with Desired Spatial Orientations: Expansion of Chemical Composition Scope Sangho Cho, Fan Yang, Guorong Sun,* Michael J. Eller, Corrie Clark, Emile A. Schweikert, James W. Thackeray, Peter Trefonas, Karen L. Wooley* - 1 - ((Supporting Information should be included here for submission only; for publication, please provide Supporting Information as a separate PDF file.)) Copyright WILEY-VCH Verlag GmbH Co. KGaA, 69469 Weinheim, Germany, 2013. Supporting Information for Macromol. Rapid Commun., DOI: 10.1002/marc.201300845 Directing Self-assembly of Nanoscopic Cylindrical Diblock Brush Terpolymers into Films with Desired Spatial Orientations: Expansion of Chemical Composition Scope Sangho Cho, Fan Yang, Guorong Sun, * Michael J. Eller, Corrie Clark, Emile A. Schweikert, James W. Thackeray, Peter Trefonas, and Karen L. Wooley * - 2 - Experimental Section Materials. The modified Grubbs catalyst, [1] 4-hydroxystyrene (pHS), [2] 2,3,5,6- tetrafluoro-4-hydroxystyrene (TFpHS), [3] NB-CTA, [4] macromonomers 1, 2, and 6–8, [5] and control brushes I and II [5] were synthesized according to the literature reports. The 2,2,2- trifluoroethyl methacrylate (TFEMA) was purchased from Aldrich and purified by passing through a neutral alumina column to remove the inhibitor. The 1,1,1-trifluoro-2- (trifluoromethyl)-2-hydroxy-4-methyl-5-pentyl methacrylate (BTFHMBMA) was purchased from Aldrich and used without further purification. Other chemicals were purchased from Aldrich, Acros, and VWR and were used without further purification unless otherwise noted. Prior to use, tetrahydrofuran (THF) was distilled over sodium and stored under N2. Dichloromethan