Arsenate removal from aqueous solutions using modified red mud.pdf

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Arsenate removal from aqueous solutions using modified red mud.pdf

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Arsenate removal from aqueous solutions using modified red mud

Ar o s w c C r ? K 1 i t h a I ( T U m a r u o a ( 0 dAvailable online at Journal of Hazardous Materials 152 (2008) 486–492 Arsenate removal from aqueous solutions using modified red mud Shuwu Zhang a, Changjun Liu b, Zhaokun Luan a,?, Xianjia Peng a, Haijing Ren a, Jun Wang a a State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085, PR China b Shandong Aluminium Co. Ltd., Shandong 255061, PR China Received 14 March 2007; received in revised form 11 June 2007; accepted 3 July 2007 Available online 17 July 2007 bstract Red mud (RM), a waste tailing from alumina production, was modified with FeCl3 for the removal of arsenate from water. The RM and modified ed mud (MRM) were characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD) microanalysis. Adsorption of arsenate n modified red mud (MRM) was studied as a function of time, pH, and coexisting ions. Equilibrium time for arsenate removal was 24 h. Solution pH ignificantly affected the adsorption, and the adsorption capacity increased with the decrease in pH. Langmuir and Freundlich isotherms equation ere used to fit the adsorption isotherms. The Langmuir isotherm was the best-fit adsorption isotherm model for the experimental data. Adsorption apacity of MRM was found to be 68.5 mg/g, 50.6 mg/g and 23.2 mg/g at pH 6, 7 and 9, respectively. NO3? had little effect on the adsorption. a2+ enhanced the adsorption, while HCO3? decreased the adsorption. MRM could be regenerated with NaOH, and the regeneration efficiency eached 92.1% when the concentration of NaOH was 0.2 mol/L. 2007 Elsevier B.V. All rights reserved. rm; F a c o a u o h p p r d t ieywords: Red mud; Modified red mud; Arsenate adsorption; Langmuir isothe . Introduction Arsenate is a widespread toxic contaminant in water and ts pollution in ground water has been found in many coun- ries in the world [1]. Human poisoning and deat