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Foaming polypropylene prepared by a novel one-step新型一步法制备发泡用PP.pdf

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Foaming polypropylene prepared by a novel one-step新型一步法制备发泡用PP

J Porous Mater (2006) 13: 297–301 DOI 10.1007/s10934-006-8020-7 Foaming polypropylene prepared by a novel one-step silane-grafting and crosslinking method Guojun Song · Shujing Yang · Chao Yang · Xilin She C? Springer Science + Business Media, LLC 2006 Abstract High-melt-strength polypropylene (HMSPP) used for foaming was prepared by a novel one-step of silane grafting and crosslinking of a normal isotactic polypropy- lene (IPP) in a twin-screw extruder. The HMSPP has been achieved using vinyl unsaturated silane with long chain as a grafting monomer, benzoyl peroxide (BPO) as an initiator, styrene as a coagent, trace amounts of water as a catalyst for crosslinking. The function of each agent in the formulation for the IPP modification was investigated. The results indi- cate that all of the agents are effective and necessary, and the proportions of the components, especially BPO, highly influenced the melt flow rate (MFR) of the HMSPP. Due to the presence of traced water in the system, the crosslinking of IPP is accompanied by the grafting of silane, which leads to a one-step production of crosslinked IPP. A high-qualified foam with uniform, closed and independent cells were fab- ricated from the HMSPP with appropriate MFR. With the decrement of the MFR of the HMSPP, the average size of the cells and the number of the unclosed cells decrease while the density of the cells increases. Keywords High-melt-strength polypropylene · Grafting and crosslinking · Unsaturated silane · Foaming G. Song () · S. Yang College of Materials, Beijing University of Chemical Technology, Beijing 100029 China G. Song · C. Yang · X. She College of Chemical Engineering, Qingdao University, Qingdao 266071 China e-mail: songguojun@ 1. Introduction As a new type of material, polypropylene (PP) foams have developed rapidly in recent years. Because of their excel- lent properties and degradability, PP foams have replaced many traditional foams, such as polyurethane, polystyrene, and polyethylen