Lammelar phase of diblock copolymer melt under shear kinetics and.pdfVIP

下载本文档

3
0
约1.06万字
约 15页
2017-04-13 发布于江苏
举报
版权申诉

Lammelar phase of diblock copolymer melt under shear kinetics and.pdf

1、本文档共15页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
8、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

Lammelar phase of diblock copolymer melt under shear kinetics and

Lammelar phase of diblock copolymer melt under shear: kineticsand conformational analysis.A.V. Zvelindovsky, G.J.A. Sevink, B.A.C. van Vlimmeren, N.M. Maurits, J.G.E.M. FraaijeDept. Biophysical Chemistry, University of Groningen,Nijenborgh 4, 9747 AG Groningen, The NetherlandsShort title: Lammelar phase of copolymer melt under shear.Key words: shear, polymer, lammelar, density functional.Address for proofs:Dr A V Zvelindovsky,Dept. Biophys. Chem.,University of Groningen,Nijenborgh 4, 9747 AG Groningen,The Netherlands 1 Abstract3D computer simulations of lammelar phase of a diblock copolymer meltunder simple steady shear are performed. The polymer system is describedby the density functional as a collection of Gaussian chains in a mean eldenvironment. The 3D mesophase morphology is obtained as a solution of adiusion-convection equation with random noise eld. Here, an analysis ofpolymer chain conformations in lamellae is considered. 2 Because of the wide area of industrial applications the behaviour of complex polymersystems in shear ows is intensively studied both experimentally and theoretically [1{3].The stability of morphology structures and phase transitions in complex polymer liquids inshear have been investigated by many authors [4{7]. During the last years the kinetics ofmorphologies of complex uids in applied external shear has also been studied by computersimulation techniques using time dependent Landau-Ginzburg models [8{13]. These modelsare based on traditional free energy expansion methods [14{16] which contain only the basicphysics of phase separation [17]. In contrast to these phenomenological theories we do nottruncate the free energy at a certain level, but rather retain the full polymer path integralby a numerical procedure [17{23]. Recently Kawakatsu and Doi started to use a similarapproach [24,25].Calculation of polymer path integrals is computationally very intensive and requiresecient numerical techniques. However it allows us to describe