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Microbial reduction of chlorite and uranium followed by air oxidation.pdf

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Microbial reduction of chlorite and uranium followed by air oxidation

Chemical Geology 283 (2011) 242–250 Contents lists available at ScienceDirect Chemical Geology j ourna l homepage: www.e lsev ie / locate /chemgeoMicrobial reduction of chlorite and uranium followed by air oxidation Gengxin Zhang a, William D. Burgos b,?, John M. Senko c, Michael E. Bishop d, Hailiang Dong d, Maxim I. Boyanov e, Kenneth M. Kemner e a Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing, China b Department of Civil and Environmental Engineering, The Pennsylvania State University, University Park, PA, USA c Department of Geological and Environmental Sciences, University of Akron, Akron, OH, USA d Department of Geology, Miami University, Oxford, OH, USA e Biosciences Division, Argonne National Laboratory, Argonne, IL, USA? Corresponding author at: Dept. of Civil and Env Pennsylvania State University, 212 Sackett Building, Un USA. Tel.: +1 814 863 0578; fax: +1 814 863 7304. E-mail address: wdb3@ (W.D. Burgos). 0009-2541/$ – see front matter ? 2011 Elsevier B.V. A doi:10.1016/j.chemgeo.2011.01.021a b s t r a c ta r t i c l e i n f oArticle history: Received 26 July 2010 Received in revised form 24 January 2011 Accepted 25 January 2011 Available online 3 February 2011 Editor: J. Fein Keywords: Smectites Phyllosilicates Uraninite Iron reductionTo evaluate the stability of biogenic nanoparticulate U(IV) in the presence of an Fe(II)-rich iron-bearing phyllosilicate, we examined the reduction of structural Fe(III) in chlorite CCa-2 and uranium(VI) by Shewanella oneidensis MR-1, and the reoxidation of these minerals (after pasteurization) via the introduction of oxygen. Bioreduction experiments were conducted with combinations of chlorite, U(VI), and anthraquinone-2,6-disulfonate (AQDS). Abiotic experiments were conducted to quantify the reduction of U(VI) by chemically-reduced chlorite-associated Fe(II), the oxidation of nanoparticulate U(IV) by unaltered structural Fe(III) in chlorite, and the sorption of U(VI) to chlorite, to elucida