-利用高铝粉煤灰合成堇青石陶瓷材料的制备研究学位论文.docVIP

第  PAGE 38 页 利用高铝粉煤灰合成堇青石陶瓷材料的制备研究 专业：材料科学与工程 学生：张政 指导老师：马立建 摘要 利用高铝粉煤灰（Al2O337.22%、SiO246%）为主要原料制备堇青石，添加适量的镁砂工业烧结镁砂 （MgO98.2%），以及少量的硅微粉（SiO2 96%），按照堇青石的理论配方（MgO 13.8%,Al2O3 34.9% ,SiO2 51.3%）进行配比。试样通过压力成型机进行压制成型，成型压力为120MPa。烧结试样分别在1150℃,1200℃,1250℃,1270℃,1290℃,1310℃六个温度下进行。烧结试样删除 通过对烧结试样的力学性能、热学性能和微观结构的分析，确定制备堇青石的最佳烧结工艺烧结工艺路线 。实验结果表明：以粉煤灰、硅微粉和工业烧结镁砂为原材料，通过对烧结体进行X-射线衍射（XRD）和扫描电子显微镜（SEM）分析，发现成功合成了堇青石陶瓷材料。通过对烧结体进行X-射线衍射（XRD）和扫描电子显微镜（SEM）分析，结果表明: 以高铝粉煤灰、工业烧结镁砂和硅微粉为原料,成功合成了堇青石陶瓷材料。 烧结体中主要以β-堇青石和α-堇青石相存在，还有少量的镁铝尖晶石，蓝晶石，铁堇青石，印度石等矿物相生成。.抗压强度，体积收缩率，体积密度，随温度的升高而增大；气孔率，吸水率则随温度的升高而降低；线膨胀系数先随温度升高而降低，当烧结温度达到1200℃时，线膨胀系数略有提升。 关键词：堇青石，微观结构，陶瓷材料，热膨胀系数 Abstract Use high-alumina fly ash（Al2O3 37.22%、SiO2 46%）as the main raw material preparation of cordierite, add appropriate amount of magnesite (MgO 98.2%), as well as a small amount of Silicon Powder (SiO2 96%) In accordance with注意英语语法问题 the theoretical formulation of cordierite (MgO 13.8%, Al2O3 34.9%, SiO2 51.3%) to the ratio,.Sample through pressure molding machine pressing, molding pressure 120MPa. And were sintered at 1150℃,1200℃,1250℃,1270℃,1290℃,1310℃six temperature. Sintered samples sintered samples through mechanical properties, thermal properties and microstructure analysis to determine the optimum sintering process cordierite Experimental results show that: Fly ash, silica fume and industrial sintered magnesia as raw material, through the sintered body X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis, we found successfully synthesized cordierite ceramic material. Sintered body mainly in the β-α-cordierite and cordierite phase exists, there is a small amount of magnesium aluminate spinel, kyanite, iron cordierite, India stone and other mineral phase formation. strength, the volume shrinkage ratio, bulk density, with the increase of the sintering temperature; porosity, water absorption with the sinterin