5月16171920WalterKaminsky教授讲座.docVIP

5月16-17、19-20Walter?Kaminsky教授讲座 Kaminsky教授是烯烃聚合茂金属催化技术的发明人，烯烃聚合领域全球最著名的科学家之一，由于其发明的茂金属催化技术为烯烃聚合领域带来了革命性的进步，因此曾被预测为诺贝尔化学奖最有希望的得主。Kaminsky教授是德国汉堡科学院成员、英国皇家化学会荣誉会士。曾担任汉堡大学化学系主任。 Kaminsky教授将安排4个讲座、共10小时，具体时间安排与讲座题目如下： May?16th???????????1:30-4:00?pm????????????Lecture?1:?Discovery?of Methylaluminoxane?and?the?Use?for?Olefin?Polymerization； May?17th???????????1:30-4:00?pm????????????Lecture?2:?Cycloolefin, Butadiene,?and?Styrene?Homo-?and?Copolymerization?by?Single-site?Catalysts; May?19th???????????1:30-4:00?pm? Lecture?3:?Short?and?Long?Chain?Branched Polyolefins?by?Metallocene?Catalysts; May?20th????????? 1:30-4:00?pm ?Lecture?4:?Polyolefin?Bio-?andNanocomposite?Materials?by?In-situ?Polymerization.讲座摘要： The?discovery?of?methylaluminoxane?(MAO)?opens?up?the?formation?of?catalysts which?show?only?one?active?site?(single?site?catalysts)?and?result?in extremely?high?polymerization?activities.?If?metallocenes,?especially zirconocenes?but?also?titanocenes?and?other?transition?metal?compounds?aretreated?with?MAO,?then?catalysts?are?acquired?that?allow?the?polymerization of?up?to?100?tons?of?ethylene?per?g?of?zirconium.?Polyolefins?synthesized?by metallocene/MAO?have?a?molecular?weight?distribution?of?2.?With?chiral metallocenes?it?is?possible?to?obtain?isotactic,?syndiotactic,?or?atactic polypropylenes?in?a?quality?which?was?unreached?before.?Metallocene catalysts?are?particularly?important?for?the?polymerization?of?cycloolefins (cyclopentene,?norbornene).?Only?the?double?bond?is?opened?and?not?the?ring.?Crystalline?polycycloolefins?are?retendered,?that?have?extremely?highmelting?points?up?to?380°C.?These?catalysts?allow?copolymerizations?to?be controlled?precisely.?Better?than?Ziegler-?Natta?catalysts?they?are?able?to copolymerize?ethylene?or?propylene?with?other?1-olefins.?Alternating copolymers?can?be?obtained,?too.??In?recent?years,?a?lot?of?research?in academic?and?industrial?laboratories?has??focused?on?the?field?of?polyolefinnanocomposites?because?of?their?high