V-OMS2催化氧化醇的性能.docx

河南师范大学 本科毕业论文 学号：1003114071 Mo掺杂K-OMS-2催化剂的制备及其 催化选择氧化醇研究 学院名称： 化学化工学院 专业名称： 化学 年级班别： 10级化学三班 姓 名： 崔聪聪 指导教师： 汤清虎 2014 年 5 月 河南师范大学本科毕业论文 PAGE \* MERGEFORMAT13 Mo掺杂K-OMS-2催化剂的制备及其催化选择氧化醇研究 摘 要 运用水热法制备了不同Mo/Mn比例的Mo-OMS-2催化剂，并以氧分子为氧化剂测试了催化剂对苯甲醇选择氧化的反应性能。不同n(Mo)/n(Mn)比例对催化剂的催化性能有重要的影响，运用合适比例的氧化物催化剂能够取得相比来说更好的催化性能。当n(Mo)/n(Mn)=6%时，催化剂的催化活性最高，苯甲醇转化率可达到60.44%。X-射线衍射结果表明，随着掺杂比例的提高，所产生的催化剂的晶胞大小逐渐减小，是的催化效率得到提高。当n(Mo)/n(Mn)小于6%时，能够形成Mo掺杂的二氧化锰分子筛，且合成的Mo-Mn-O双组分催化剂主要以短程有序的非晶结构形式存在的。但当n(Mo)/n(Mn)比较高于6%时，会产生不同晶型的MnO2、MoO3结晶，从而使催化剂活性明显下降。 关键词 Mo-OMS-2，醇氧化，选择氧化，分子氧，氧化 Synthesis of Mo Mixed OMS-2 Catalysts and Its Catalytic Performance in Selective Oxidation of Alcohols Abstract Hydrothermal prepared using different Mo / Mn ratio of the Mo-OMS-2 catalyst and molecular oxygen as the oxidant tested for selective oxidation of benzyl alcohol catalyst reaction performance. Different n (Mo) / n (Mn) have a significant impact on the proportion of the catalytic properties of the catalyst, the use of an appropriate proportion of oxide catalysts can achieve better catalytic performance is compared. When n (Mo) / n (Mn) = 6%, the highest catalytic activity of the catalyst, the conversion of benzyl alcohol to reach 60.44%. X-ray diffraction results show that with the doping ratio increases, the unit cell size of the resulting catalyst decreases, the catalytic efficiency is improved. Mo-Mn-O catalysts bicomponent when n (Mo) / n (Mn) of less than 6%, Mo can be formed of manganese dioxide doped zeolite, and mainly in the synthesis of short-range order structure present in an amorphous form . But when n (Mo) / n (Mn) compare more than 6%, will produce different polymorphs of MnO2, MoO3 crystallization, so that the catalyst activity was significantly decreased. Keyword Mo-OMS-2，alcohol oxidation，Selective Oxidation，molecular oxygen，oxidation 前言 醇氧化制羰基化合物是有机合成的重要反应之一，广泛