CaO絮凝沉淀_树脂吸附两步法处理制药废水.pdf

化 工 进 展 2011 年第 30 卷第 3 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·671· 研究开发 CaO 絮凝沉淀-树脂吸附两步法处理制药废水 张 鑫，白玲玲，黄佳佳，赵林秀，原思国 （郑州大学化工与能源学院，河南 郑州 450001） 摘 要：磺胺间甲氧嘧啶类药物在生产过程中产生大量高浓度和高 COD 废水。本工作以前期合成的非苯乙烯骨 架吸附树脂为基本吸附材料，开展了 CaO 絮凝沉淀-树脂吸附两步法处理此类废水的研究。结果表明：废水的 COD 可从原来的 11 000 mg/L 降至 321 mg/L，絮凝沉淀、树脂吸附的 COD 去除率分别达 84.33%和 81.66%（总 去除率≥97%）。此废水处理工艺简单、运行费用低，树脂经 5 次吸附-脱附后仍保持良好吸附性能，具有很好的 实际应用前景。 关键词：絮凝沉淀；树脂吸附；制药废水 中图分类号：X 703 文献标志码：A 文章编号：1000–6613（2011）03–0671–05 Treatment of pharmaceutical wastewater by CaO flocculation sedimentation and resin adsorption ZHANG Xin，BAI Lingling，HUANG Jiajia，ZHAO Linxiu，YUAN Siguo （School of Chemical Engineering and Energy，Zhengzhou University，Zhengzhou 450001，Henan，China） Abstract：A large amount of high chemical oxygen demand（COD）wastewater was generated in the synthesis of sulf amonomethoxine drugs. Based on a novel non-styrene adsorptive resin synthesized by the authors，the research on the treatment of pharmaceutical wastewater was performed by the process of CaO flocculation sedimentation and resin adsorption. The results showed that COD of the original wastewater could be decreased to 321 mg/L from 11000 mg/L by the novel process. 84.33% and 81.66% COD removal percentages could be achieved by CaO flocculation sedimentation and resin adsorption ， and the total COD removal efficiency was over 97%. After 5 times of adsorption-desorption cycles，the resins still kept high adsorptive capabilities. This simple and economical technique for pharmaceutical wastewater treatment shows good prospects for practical application．