离子型表面活性剂中痕量铜的直接检测.pdf

New study on direct detection of trace copper in the presence of ionic surfactant Shuguo Gong, Jianjun Xia, Wanzhi Wei* ,Jian Yin, Jinxiang Zeng, Xiaoying Liu, Xiurong Zhai State Key Laboratory of Chem/Biosensing and Chemometrics College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China. Abstract The usual methods for the quantification A new method for the direct detection of trace of copper include neutron activation analysis, copper in the presence of ionic surfactant was atomic absorption spectrometry, and developed, based on the response of differential inductively coupled plasma-mass pulse anodic stripping voltammetry at a gold spectrometry [1]. All these methods are based electrode modified with self-assembled monolayer on expensive and sophisticated instruments. of 2-mercaptobenzimidazole(MBI).Experimental Their application in continuous monitoring results indicated that MBI monolayer could and on site detection is greatly limited. prevent electrode surface fouling by ionic The electrochemical techniques, surfactant and that after preconcentration, copper especially stripping voltammetry, for the down to 0.01 μmol l-1 in the presence of 0.5 mg trace analysis of metal ions obtained ml-1 hexadecyl trimethyl ammonium bromide considerable interest because of its low cost, could be detected. The features of the new method easy operation, good sensitivity, high were to be simple, sensitive and low-cost. selectivity and accuracy [2]. However, the Keywords: direct detection, trace copper, ionic dominating problem of electrochemical surfactant, modified electrode, stripping methods when applied in environmental voltammetry. analysis was contamination on the surfaces