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用于吸附的MOFs——H2储存 刘凯 2014301040058 Abstract: Hydrogen storage in metal–organic frameworks (MOFs), or porous coordination polymers, has been extensively investigated in the last years and this review is to serve as a kind of looking back to the MOFs developed in last years. Preparation and activation, capacity and disadvantages have been discussed on this review. Introduction H2, as an energy carrier (like electricity), not a primary energy source (like coal), is one of the most promising candidates for the replacement of current carbon-based energy sources with high energy density. However, liquid of H2 is very difficult to storage and deliver because of its high energy density, weight, high pressure and the special techniques of pressurization. So DOE of America has set up the targets for on-board H2 storage systems with the concept that higher efficiency fuel-cell power sources will replace current carbon-based energy source in future vehicles. Unfortunately, none of the candidate materials developed so-far (or before MOFs) has satisfied the DOE target yet. MOFs, as one of the promising hydrogen storage materials38, has very large surfaces inside about 103~104 m2·g-1. The H2 storage capacity mainly depends on the surface area and pore volume. However, The main limitation of use of these sorbents as H2 storage materials is weak van der Waals interaction energy between H2 and the surface of the sorbents, which results the weak absorption at ambient temperature in spite of high storage capacities at liquid nitrogen temperature and high pressures. Therefore, Research is being directed toward the synthesis of highly porous materials that would have enhanced interaction energies with gaseous H2. The positive side of these materials is the fast adsorption and desorption kinetics. In 2003, Yaghi and coworkers reported the first MOF-based hydrogen storage result N. L. Rosi, J. Eckert, M. Eddaoudi, D. T. Vodak, J. Kim, M. O’Keeffe and O. M. Yaghi, Science, 2003, 300, 1127.