化学计量比LaMg对铸态及退火态La-Mg-Ni系A2B7型电极合金结构及电化学性能的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 25(2015) 1968−1977 Effects of stoichiometric ratio La/Mg on structures and electrochemical performances of as-cast and annealed La−Mg−Ni-based A B -type electrode alloys 2 7 1,2 2 2 2 1 2 Yang-huan ZHANG , Tai YANG , Ting-ting ZHAI , Ze-ming YUAN , Guo-fang ZHANG , Shi-hai GUO 1. Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, China; 2. Department of Functional Material Research, Central Iron and Steel Research Institute, Beijing 100081, China Received 15 August 2014; accepted 29 October 2014 Abstract: In order to investigate the influences of the stoichiometric ratio of La/Mg (increasing La and decreasing Mg on the same mole ratio) on the structure and electrochemical performances of the La−Mg−Ni-based A B -type electrode alloy, the as-cast and the 2 7 annealed ternary La0.8+xMg0.2–xNi3.5 (x=0−0.05) electrode alloys were prepared. The characterization of electrode alloys by X-ray diffraction (XRD) and scanning electron microscopy (SEM) shows that all the as-cast and the annealed alloys hold two major phases of (La,Mg) Ni and LaNi as well as a residual phase of LaNi . Moreover, the increase of La/Mg ratio brings on a decline of 2 7 5