微弧氧化处理对AA7075铝合金在3.5％ NaCl溶液中局部腐蚀行为的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 22(2012) 686−693 Thermodynamics and kinetics of adsorption of molybdenum blue with D301 ion exchange resin ZHAO Zhong-wei1, 2, XU Xiao-yang1, 2, CHEN Xing-yu1, HUO Guang-sheng1, CHEN Ai-liang1, LIU Xu-heng2, XU Hui3 1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China; 2. Hunan Key Laboratory for Metallurgy and Material Processing of Rare Metals, Changsha 410083, China; 3. School of Physical Science and Technology, Central South University, Changsha 410083, China Received 21 January 2011; accepted 2 June 2011 Abstract: The adsorption behavior of D301 for molybdenum blue was investigated. The thermodynamics parameters in adsorption process were calculated and the adsorption kinetics was studied. The experimental results show that the adsorption characteristic of D301 for molybdenum blue fits well with the Freundlich adsorption isotherm equation. In the adsorption process of D301 for molybdenum blue, both the enthalpy change ΔH and entropy change ΔS are positive, while the free energy change ΔG is negative when temperatures are in the range of 303−333 K. It is indicated that the adsorption is a spontaneous and endothermic process, and the elevated temperatures benefit to the adsorption. Kinetic studies show that the kinetic data are well described by double driving-force model, and the adsorption rate of molybdenum blue on D301 is controlled by the intraparticle diffusion during the adsorption process. The total kinetic equation is determined. Key words: Ni−Mo ore; molybdenum blue; adsorption; thermodynamics; kinetics 1 Introduction In South China, there are abundant lower cambrian black shales (Ni−Mo ores) which are rich in Ni, Mo, V, Cu, Co,