胶黏剂基础之11——氰基丙烯酸酯胶黏剂(英文版)(常用的502,504系列胶)CyanoacrylateAdhesives.pdf

Cyanoacrylate Adhesives SpecialChem - Oct 8, 2003 Edward M. Petrie, Member of SpecialChem Technical Expert Team. Introduction Cyanoacrylate adhesives became well known after their commercial introduction in the early 1970s in the consumer market. These unique products were initially referred to as superglue. The name is well deserved since cyanoacrylate adhesives have certain characteristics like no other adhesive. These adhesives are solvent-free, one-part formulations that cure rapidly when pressed into a thin film between two substrates. Perhaps no other adhesive bonds so rapidly and so easily to such a variety of substrates as does a cyanoacrylate. Early generations of cyanoacrylate adhesives had significant performance limitations. Since they were essentially thermoplastic in nature, cyanoacrylate adhesives exhibited poor thermal and chemical resistance. Since they were hard and brittle when cured, they exhibited poor impact and peel properties. These drawbacks limited the application of cyanoacrylate adhesives to high volume assembly operations with minimal performance requirements. Newer formulations, however, have greatly improved the performance properties of these instant adhesives. New products continue to offer the ease of use of a cyanoacrylate but now with the added performance properties of a truly structural adhesive. Table 1 summarizes the general benefits and limitations of todays cyanoacrylate adhesive systems. Benefits Limitations Excellent Adhesion to a wide variety of substrates Blooming/frosting Difficult to cure fillet or exposed liquid Substrate variety adhesive without activator Simple cure mechanism Limited gap cure