镍锰酸锂改性问题.pdfVIP

Journal of Materials Chemistry A PAPER View Article Online View Journal | View Issue Polyhedral LiNi0.5Mn1.5O4 with excellent electrochemical properties for lithium-ion Cite this: J. Mater. Chem. A,2014,2, 12835 batteries? Zhanjun Chen,a Ruirui Zhao,a Peng Du,a Hang Hu,a Tao Wang,a Licai Zhua and Hongyu Chen*abc Alternative micro-sized LiNi0.5Mn1.5O4 spinels with octahedral structure (showing only one type of {111} crystal face) or chamfered polyhedral structure with extra other faces have been synthesized via a controllable method. A possible growth model, complexing–pyrolyzing-oriented, is also proposed for the formation of chamfered polyhedral LiNi0.5Mn1.5O4 spinel based on the experimental results in this à1 paper. The chamfered polyhedral LiNi0.5Mn1.5O4 can provide a large capacity of 103 mA h g even at a discharge rate as high as 50 C, which is far superior to that of the octahedral structure. Besides, the capacity retentions of the chamfered polyhedral composites are found to be 90.82% at 25 C after 500 cycles and 90.00% at 55 C after 200 cycles, which are also better than those of the oc