IGCC中水煤浆气化炉数学平衡模型研究.pdfVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：084073 IGCC 中水煤浆气化炉数学平衡模型研究 何翔 1 金晶 1 张忠孝 1 代百乾 1 陈雷 1 王婧 1 庞克亮 2 陈晓利 2 (1 上海理工大学动力工程学院 上海 200093；2 国家电站燃烧工程技术研究中心 沈阳 110034) (第一作者电话 Email：seanjastyt@163.com) 摘 要 利用质量、能量和化学平衡建立了 IGCC 电站中水煤浆进料式气流床气化炉的数学平衡模型。 用于预测气化炉出口合成气流量、成分以及碳转化率。本模型特点在于从数学和气化机理中合理假设 了两个化学反应平衡式，再采取范特霍夫公式、物质生成热和吉布斯自由能的综合推导，得出化学平 衡常数 K 和温度的关系，最后利用牛顿法求解方程组。模型计算结果与相关文献的模拟、实际运行结 果进行对比，数据吻合较好。 关键词 整体煤气化联合循环; 水煤浆气化炉; 气流床数学模型; 化学平衡; 模拟; 运行 Equilibrium math-model of IGCC’s slurry gasifier He Xiang1, Jin Jing1, Zhang Zhongxiao1, Dai Baiqian1, Chen Lei1, Wang Jing1, Pang Keliang2, Chen Xiaoli2 (1Department of Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China；2.National Power Plant Combustion Research Center, Shenyang 10034, China) Abstract: Construct an equilibrium math-model of slurry gasification about entrained flow gasifier in IGCC based on equality, energy and chemistry balance in order to predict syngas’s components, flow-rate and carbon’s conversion. Hypothesis of two chemical equilibrium equations are in terms of the deducing from math, and gasification mechanism. The Van’t Hoff’s law, substance’s formation heat and Gibbs free energy are combined to gain the chemical equilibrium constant K’s value. So do the relation between K and temperature. Apply Newton-Raphson method to finish the equations’ solution. The calculation’s results are compared with other papers’ simulations and operation, in which the figures match well. Keywords: IGCC, slurry gasifier, entrained flow math-model, chemical equilibrium, simulation, operation 0 前言