2.4机械活化对表面效应的影响.doc

*收稿日期： 基金项目：国家自然科学基金资助、广西大学广西有色金属及特色材料加工重点实验室开放基金（GXKFJ16-01）；广西博士后专项资金、广西高校矿物工程重点实验室资助项目。 作者简介：徐 明（1990—），男，陕西蓝田人，硕士研究生，主要从事矿物材料加工及应用研究。 通讯作者：杨金林（1975—），男，湖北省罗田县人，博士，副教授，主要从事矿物材料加工与应用及复杂难选矿产资源高效处理。 ZnFe2O4的制备及其酸溶特性 徐 明，杨金林，马少健 （广西大学 资源与冶金学院，南宁 530004） 摘 要：本文对分析纯的ZnO和Fe2O3超声波分散25 min后烘干，高能球磨预处理5 h后恒温焙烧制备ZnFe2O4。通过粒级筛分、XRD、SEM等检测方法，研究焙烧温度对产品粒度特征、结晶状况和微观形貌的影响。所制产品经机械活化后进行微波焙烧处理，分析其孔径和比表面积。利用插值法和响应曲面法处理硫酸浸出试验数据，研究初始酸浓度和浸出温度对铁酸锌酸溶特性的单因素影响及交互作用影响。 关键词：铁酸锌，制备，机械活化，酸溶特性 中图分类号：TB34 文献标识码：A Study on Preparation and Acid Soluble Feature of Non-nano Zinc Ferrite XU Ming, YANG Jinlin, MA Shaojian (School of Resources and Metallurgy, Guangxi University, Nanning 530004) Abstract: In this paper, based on the analytically pure ZnO and Fe2O3?as raw materials, the non-nano ZnFe2O4 was preparated by constant temperature roasting after ultrasonic dispersion for 25 min and pretreatment for 5h by high-energy ball milling. The particle size characteristics, crystallization conditions and microstructure of zinc ferrite products were researched by the method of XRD, SEM and particle size analysis under different roasting temperatures. The pore size and specific surface area of the zinc ferrite product was analyzed after mechanical activation and microwave roasting. The data of sulfuric acid leaching were analyzed by the interpolation method and response surface method. The single factor and interaction effects of initial acid concentration and leaching temperature on acid soluble properties were studyed. Keywords: zinc ferrite, preparation,  HYPERLINK C:/Documents%20and%20Settings/Administrator/Local%20Settings/Application%20Data/Yodao/DeskDict/frame/20151129212258/javascript:void(0); mechanical? HYPERLINK C:/Documents%20and%20Settings/Administrator/Local%20Settings/Application%20Data/Yodao/DeskDict/frame/20151129212258/javascript:void(0); activation, acid-soluble characteristic 铁酸锌的化学稳定性表现为适当高的温度下结构和性质均不发生改变。在各种材料特性中，实用化程度最高的方面就是制作防锈底漆等涂料[1-2]。铁酸锌不含铅、铬等重金属