APTES改性介孔二氧化硅的制备及其对重金属离子的吸附.PDFVIP

第 27 卷 第 2 期 湖 南 工 业 大 学 学 报 Vol.27No.2 2013 年 3 月 Journal of Hunan University of Technology Mar.2013 doi:10.3969/j.issn.1673-9833.2013.02.004 APTES 改性介孔二氧化硅的制备及其 对重金属离子的吸附 孙静静，许利剑，李 文，汤建新 （湖南工业大学绿色包装与生物纳米技术应用湖南省重点实验室，湖南株洲 412007） 摘 要：以介孔二氧化硅为载体，3- 氨基丙基三乙氧基硅烷（APTES）为改性剂，成功制备了氨基硅烷 改性介孔硅球。并利用透射电子显微镜、能量色散 X 射线光谱仪和傅里叶变换红外光谱仪等对制备的介孔硅 球进行了表征，同时考察了改性后的介孔硅对重金属铅的吸附效应。结果表明：通过改性处理，3-氨基丙基 三乙氧基硅烷被成功接枝到介孔硅表面；氨基功能化介孔硅溶胶吸附剂对重金属 Pb2+ 具有选择吸附特性，且 吸附量随反应原料中 APTES 含量的提高呈现出相应的增加趋势。 关键词：介孔硅；3-氨基丙基三乙氧基硅烷；改性硅球；重金属吸附 中图分类号：TQ424.26 文献标志码：A 文章编号：1673-9833(2013)02-0016-05 APTES-Modified Mesoporous Silica Preparation and Its Adsorption on Heavy Metal Ions Sun Jingjing, Xu Lijian, Li Wen，Tang Jianxin （Key Laboratory of Green Packaging and Application of Biological Nanotechnology of Hunan Province, Hunan University of Technology，Zhuzhou Hunan 412007, China） Abstract：With mesoporous silicon as carrier material and APTES as modifier, the modified mesoporous silica sphere was successfully prepared. Its microstructures were characterized by transmission electron microscope(TEM), energy dispersive x-ray Detector(EDX) and Fourier transform infrared spectrum(FI-TR), and its adsorption on the heavy metal Pb was investigated. The results indicated that the APTES was grafted onto the surface of the mesoporous silica successfully, the modified mesoporous silicon had a selective adsorption characteristics on heavy metal Pb2+, and the adsorption capacity showed improving as the increase of the APTES in reactant. Keywords：mesoporous silicon；APTES；modified silicone ball；heavy metal adsorption