catalyst.PDF

Chinese Journal of Catalysis 36 (2015) 1142–1154 催化学报 2015年 第36卷 第7期 | available at journal homepage: /locate/chnjc Article Oxidative carbonylation of phenol with a Pd-O/CeO2-nanotube catalyst # Ye Yuan, Zhimiao Wang, Hualiang An, Wei Xue *, Yanji Wang Hebei Provincial Key Laboratory of Green Chemistry High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China ARTICLE INFO ABSTRACT Article history: CeO2 nanotubes (CeO2-NT) were synthesized using carbon nanotubes as template by a liquid phase Received 22 December 2014 deposition and hydrothermal method. X-ray diffraction, transmission electron microscopy, and N2 Accepted 7 February 2015 adsorption-desorption were used to characterize the CeO2-NT. The wall of CeO2-NT was composed Published 20 July 2015 of small interconnected nanocrystallites ranging from 4 to 9 nm in size. The specific surface area of CeO2-NT was 108.8 m2/g with an outer diameter of 25 nm and length 300 nm. Supported Pd cata- Keywords: lyst, Pd-O/CeO2-NT, was prepared using CeO2-NT as the support. Temperature-programmed reduc- Diphenyl carbonate tion analysis showed that the surf