PTFE_FEVE氟碳防污涂层的表面特性与海藻附着.docVIP

——————————————————————————————————————————————— PTFE_FEVE氟碳防污涂层的表面特性与海藻附着 doi: 10.3969/j.issn.1007?9289.2010.03.015 PTFE/FEVE氟碳防污涂层的表面特性与海藻附着* 张占平，齐育红，刘 红 （大连海事大学 材料科学与工程系，大连 116026） 摘 要：以FEVE氟碳树脂为成膜物、超细PTFE粉末为低表面能功能添加剂，试制了PTFE质量百分比分别为10 %、 20 %、30 %的氟碳防污涂料，利用扫描电镜和表面形貌仪试验研究了涂层中PTFE含量对涂层表面形貌的影响，借助生物学方法、体视显微镜和图像分析方法研究了涂层表面特性对海洋微藻（舟形底栖硅藻）和大型藻（水云藻）附着的影响。结果表明，随着防污涂层中PTFE含量的增加，涂层的表面粗糙度降低，平滑性和致密性提高，涂层上底栖硅藻和水云藻的附着量随之减少。 关键词：PTFE；FEVE氟碳树脂；生物附着；表面形貌；底栖硅藻；水云藻 中图分类号：O484.4; TB383 文献标识码：A 文章编号：1007–9289(2010)03–0070–04 Settlement of Marine Algae and Morphology of PTFE/FEVE Fluorocarbon Antifouling Coatings ZHANG Zhan–ping, QI Yu–hong, LIU Hong (Department of Materials Science and Engineering, Dalian Maritime Univ, Dalian 116026) Abstract: Fluorocarbon coatings were developed with respectively 10 %, 20 % and 30 % PTFE powder. Influence of content of PTFE on surface morphology of coatings was investigated using SEM and rugometer. It was studied that the effect of coating roughness on settlement of benthic diatom and Ectocarpus with stereo microscope by image process. Results indicated that with the increase of content of PTFE in paint, surface roughness of the the coating decreases, meanwhile, benthic diatom and Ectocarpus attaching onto the coating reduce. Benthic diatoms attached much more on horizontal specimen than on the vertical one, and they tend to settle onto the surface of the coatings that there are lots of micro–cracks. These results are helpful for developing new non–toxic antifouling paints. Key words: PTFE ; FEVE resin; biofouling; morphology; benthic diatoms; ectocarpus 0 引 言 近年来，人类对海洋环境资源的开发和利用不断扩大，因海洋生物的附着污损而导致的燃料消耗、温室气体排放增加，以及结构腐蚀破坏等问题日益受到重视。在船舶、海上石油平台等大型海洋结构物表面涂装防污涂料是长期以来解决海洋生物附着污损问题的唯一得到广泛应用的既经济又高效的重要途径[1]。有机锡防污漆因其具有广谱和高效的防污效果，曾经在过去几十年中获得广泛应用。但有机锡在鱼类、贝类体内会积累，导致遗传变异等，对海洋生态环境、甚至人类健康带来危害。 收稿日期：2010–04–19 基金项目：*863计划（2009AA03Z510）； 国防基金项目（200812003） 作者简介：张占平(1963—)，男(汉)，陕西志丹人，教