加氢裂化尾油的加氢异构性能_王强.pdf

Vol. 32 No. 11 ( ) 2006-11 Journal of E ast China University of Science an T echnology ( Natural Science E ition) 1265 : 1006-3080( 2006) 11-1265-05 1, 2 1 1 2 2 王　强 , 　沈本贤 , 　凌　昊, 　贺产鸿 , 　李　坤 ( 1. 华东理工大学化工学院, 上海200237; 2. 中国石油化工股份有限 司茂名分 司, 茂名525001) : 在连续微型固定床反应装置中, 氢气分压9. 0 MPa、温度300 ～345 °C和体积空速0. 6 ～ - 1 1. 2 h 条件下评价了加氢裂化尾油的加氢异构性能。研究了反应产物的碳数分布和族组成变化, 并建立了三集总动力学模型。研究结果表明: 在合适的工艺条件下, 润滑油基础油收率可达75% 左 + 右, 粘度指数在 110 以上, 适合生产A PI II 标准的润滑油基础油。所建立的芳烃和环烷烃、长链烷 烃、轻质产物的三集总动力学模型可以较好地预测产物分布。 : 加氢裂化尾油; 加氢异构; 集总; 基础油 : O643 : A Hydroisomerization Property of Hydrocracking Tail Oil 1, 2, - 1, 1, - 2 , 2 WA N G Qiang SH EN Ben x ian LI N G H ao H E Chan hong L I K un ( 1. School of Chemical E ngineering , East China Universit of S cience and Technolog , Shanghai 200237, China; 2. Sinop ec Maoming P etrochemical Co. L td . , Maoming 525011, China) : Abstract T he hy roisomerization property of hy rocracking tail oil w as investigate un er mo erate operation con itions over a commercialize hy roisomerization catalyst. A flow micro reactor experiments w ere con ucte at the con itions of hy rogen partial pressure of 9. 0 MPa, reaction temperature ranging - 1 from 300 to 345 C, an liqui hourly space velocity ranging from 0. 6 to 1. 2 h . Carbon number an . - - group istributions w ere also stu ie T he fourth fifth Runge Kutta a