差示扫描量热法研究丙烯腈_衣康酸共聚物的热稳定化.pdfVIP

2007 65 Vol. 65, 2007 24 , ACTA CHIMICA SINICA No. 24, · · a,b a,b *,a a (a 030001) (b 100049) (DSC)(IA)[P(AN-IA)] . IA . P(AN-IA), IA , , . . Kissinger IA , IA . ; ; ; Study on Thermal Stabilization of Poly(acrylonitrile-co-itaconic acid) by Differential Scanning Calorimetry OUYANG, Qina,b CHENG, Lua,b WANG, Hao-Jing*,a SUN, Yu-Hana a ( Key Laboratory of Carbon Materials, Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001) (b Graduate University of Chinese Academy of Sciences, Beijing 100049) Abstract The effect of itaconic acid (IA), atmosphere and heating rate on the thermal stabilization of acrylonitrile copolymer with itaconic acid [P(AN-IA)] was studied by differential scanning calorimetry (DSC), showing that IA could significantly reduce the initiation temperature of the exotherm, and decrease the quantity and the rate of heat evolved in the DSC exotherm. The initiation temperature of the exotherm of P(AN-IA) was little influenced by the atmosphere, however, distinctly decreased with the enhancement of IA content in the copolymer, which implied that the initiation of nitrile cyclization reaction preceded the on- set of oxidation reaction through an ionic mechanism. Promoting heating rate resulted in a shift of the exo- therm to a higher temperature, and a more rapid liberation of heat. The activation energy was calculated with the Kissinger method, and the results showed that IA could efficiently decrease t