固体超强酸SO42-／TiO2催化合成壬基二苯胺.pdfVIP

学兔兔 化 工 进 展 ·1574· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2009年第28卷第9期 固体超强酸SO42-／TiO2催化合成壬基二苯胺 郑 彬，陈 群，何明阳 (江苏工业学院，江苏省精细石油化工重点实验室，江苏 常州 213164) 摘 要：以固体超强酸 8042-／TiO2为催化剂，通过二苯胺与壬烯发生烷基化反应制备抗氧剂壬基二苯胺。研究了 固体超强酸的煅烧温度、催化剂量、壬烯与二苯胺的比例、反应温度、反应时间和催化剂稳定性对二苯胺的转化 率和二壬基二苯胺选择性的影响。结果表明，当固体超强酸的煅烧温度为 550~C、催化剂量为 3．50g、壬烯为 l5．12 g、二苯胺为5．07 g、反应温度为140℃时，反应12 h，二苯胺的转化率达到97．3％，目标产物二壬基二苯 胺的选择性为86．4％。催化剂重复使用6次，二苯胺的转化率仍达到923％，二壬基二苯胺的选择性为80．2％。催 化剂失活的主要原因为积炭和S042的流失。 关键词：固体超强酸SO42／ZiO2；二苯胺；壬烯；抗氧剂；烷基化 中图分类号：O 625．4 文献标识码：A 文章编号：1000—6613(2009)09—1574—04 Synthesis of nonyldiphenylamine catalyzed by solid superacid 8042-／TiO2 ZHENG Bin，CHEN Qun，HEMingyang (Jiangsu Polytechnic University，Jiangsu Key Lab ofFine Peffochemical Technology，Changzhou 213164 Jiangsu，China) Abstract：Nonyldiphenylamine，an antioxidant，was synthesized by the reaction of diphenylamine with nonene under the catalysis of a solid superacid 504 ／TiO2．Several factors affecting the diphenylamine conversion and the selectivity for nonyldiphenylamine were investigated，including the calcination temperature of solid superacid，the reaction temperature and the amounts of catalyst，diphenylamine and nonene．The diphenylamine conversion reached to 97．3％ with a selectivity for the aimed product， nonyldiphenylamine，of 86-4％when the superacid was calcinated at 550℃，where the reaction was carried out at 140℃ for 12 h with 3．50 g of catalyst，5．07 g of diphenylam ine and 15．12 g of nonene． When the catalyst was reused for si