1材料与方法-农业环境科学学报.doc

铜陵矿区周边土壤蔬菜重金属转移特征 豆长明1徐德聪2,3(1，孙庆业3窦智勇3周平3 1. 安徽省环境科学研究院, 合肥 230061；2. 宿州学院特色种植业苗种生产工程技术研究中心, 宿州 234000；3. 安徽大学资源与环境工程学院, 合肥 230601) 摘要: 通过实地调查取样和室内分析，研究铜陵矿区周边菜地土壤中重金属(Cu、Zn、Pb、Cd) 向两种蔬菜（萝卜和辣椒）可食部分的转移特征。运用5种单一提取剂DTPA、EDTA、HC、NH4NO3和NH4OAC研究了土壤中重金属的生物有效性问题，并结合土壤化学性质运用多元逐步线性回归进行对比分析。结果表明NH4NO3提取态的Zn和Cd以及NH4OAC提取态的Zn均可以较好地反映重金属的生物有效性；土壤样品中的P含量对Zn和Cu析出有显著影响；与果实类蔬菜相比，根类蔬菜可食部分具有富集重金属能力。土壤-蔬菜间重金属转移系数（TF）均随土壤中重金属含量增加而减小，且由于TF与土壤提取态金属含量间能建立显著模型，因此用TF来预测蔬菜中金属含量是一个可选的方法。 关键词重金属蔬菜Transfer characteristics of heavy metals from soil to vegetable in the vicinity of Tongling mining area, China DOU Chang-ming1, XU De-cong2, 3*, ZHOU Xiao-tie1, SUN Qing-ye3, DOU Zhi-yong3, ZHOU Ping3 (1. Anhui Academy of Environmental Science, 230061, Hefei, China; 2. Characteristic Planting Seedling Production Engineering Technology Research Center, Suzhou University, 234000, Suzhou, China; 3. School of Resource and Environment, Anhui University, 230601, Hefei, China) Abstract: Based on field investigation and laboratory analysis, the transfer characteristics of heavy metals(Cu、Zn、Pb、Cd from soil to the edible parts of two vegetable species were studied. All the plant and corresponding surface soil samples were collected from the vicinity of Tongling mining area, China. Five extraction procedure methods (DTPA、EDTA、HC、NH4NO3 and NH4OAC) were used to analyze the bioavailability of metals, and the results were compared by stepwise multiple linear regression analysis. It showed that Zn extracted by NH4NO3 and NH4OAC and Cd extracted by NH4NO3 had good correlation with metal concentrations in the edible part of researched vegetables. Extracted Pb by all the five extractants had no significant correlation with Pb concentrations in the two vegetables. Phosphorus content in soil was also a determinant variable in the estimation of extractable Zn and Cu. Root vegetables showed better accumulation of all metals than fruit vegetables in their edible parts. For all the metals studied, there was a signi?cant re