煤气化污水化工处理新流程.pdf

学兔兔 化 工 进 展 2009年第28卷第12期 CHEMICAL INDUSTRy AND ENGINEERING PROGRESS ·2253· 煤气化污水化工处理新流程 陈 赞 ，余振江 ，盖恒军 ，周永涛 ，高亚楼 ，章莉娟1钱 宇 (。华南理工大学化学与化工学院，广东广州510640； 中煤龙化哈尔滨煤化工有限公司，黑龙江 哈尔滨 154854) 摘 要：针对鲁奇加压气化．T-艺产生的煤气化污水处理现有流程特点提出一种新的化X-处理过程，并实现了工业 化。分别介绍煤气化污水化工流程处理的新老过程。新流程中，采用酸水汽提塔同时脱除煤气化污水中的氨气和 酸性气体，氨气脱除后的煤气化污水pH值由原先的9～l1降低至7以下，有利于后续溶剂萃取脱酚。而萃取溶 剂甲基异丁基甲酮(MIBK)相比二异丙醚(DIPE)对污水中单元酚和多元酚有更高的分配系数，MIBK的萃取 应用将从污水中回收更多的酚类成分，从而在煤气化污水生化处理前COD能进一步降低。 关键词：煤气化污水；酸水汽提塔；_S-异丙醚；甲基异丁基甲酮；萃取 中图分类号：X703 文献标识码：A 文章编号：1000—6613(2009)12—2253—04 A novel chemical process for c0al—gasificati0n wastewater treatment CHENYun ，YUZhenjiang ，GAIHeng]un ，ZHOUYongtao ，GAO Yalou ，ZHANGLijuan ，QIANYu (。School ofChemical Engineering，South China University ofTechnology，Guangzhou 5 10640，Guangdong，China； China Coal Longhua Harbin Coal Chemical Industry Co．Ltd．，Harbin 154854，Heilongjiang，China) Abstract：A novel chemical process iS introduced for the treatment of coal—gasification wastewater produced from Lurqi gasification，and the process has been industrially realized．Ammonia and acidic gas in coal—gasification wastewater are removed through a sour water stripping tower in the new process，through which the pH value of the treated wastewater is decreased from 9一 ll tO 7，and hence it iS beneficial to the subsequent solvent extraction for phenols．The distribution coefficients of MIBK to phenol and polyhydric phenols are greater than those of DIPE．The application of MIBK as extraction solvent would recover more phenolic substances from wastewater than DIPE．The C0D value would be further reduced before the coa1．gasification wastewater flowed into the biochemical treatment． Ke