不同结构的ACR核壳粒子增韧聚碳酸酯的机理_徐会军.pdfVIP

DOI :10.14133/j.cnki .1008 -9357.2009.03.009 　　　　　　 Vol.22 No.3 276 　　　　Journal of Fu nctional Polym ers 2009 9 ACR 徐会军, 　唐颂超, 　杨　龙 (华东理工大学材料科学与工程学院, 上海市先进聚合物材料重点实 室, 上海200237) 　:　用自制的核壳结构丙烯酸酯类共聚物(AC R)与聚碳酸酯(PC )共混制成共混材料(PC- ACR),考察了AC R 的粒径以及AC R 的壳层引入甲基丙烯酸缩水甘油酯(GM A )单体后对PC- ACR 共混物冲击强度的影响。壳层引入GM A 的AC R 提高PC 缺口韧性的效果并不明显;而 ACR 的粒径对PC-ACR 冲击韧性的影响较大。运用J 积分断裂韧性分析比较了AC R 粒径对共 混物断裂过程中弹性形变区-塑性形变区能量吸收能力的影响。塑性形变作为主要能量吸收途径 在提高共混物韧性方面起主要作用,粒径为177.5 nm 的ACR 提高PC 的断裂韧性效果最好,与悬 臂梁冲击实 得到的冲击强度数据 一致。 :　聚碳酸酯;ACR;GM A;冲击强度;断裂韧性 + :　T Q323.4 1　　:　A 　　:　1008-9357 (2009)03-0276-06 Mechanism of Polycarbonate Toughened by ACR Core-Shell Particles with Different Structures XU Hui-jun, 　TANG Song-chao, 　YANG Long (Key Laboratory for Ad anced Polymer M aterials of Shanghai,School of Materials Science and Engineering,East China Uni ersity of S cience and Technology,Shanghai 200237,China) Abstract:　PC-ACR blends w as prepared by blending poly carbonate (PC )w ith acrylic copolymer (ACR) w hich w as self-made.Influence of modifier size and gly cidyl methacrylate (GM A )introduced into shell of ACR on impact strength of PC-AC R blends w ere in estigated.Increasing of notch toughness of PC-AC R w hich ACR shell had introduced GMA is not effecti e.Whereas diameter of ACR has great influence on impact toughness of PC-ACR blends .The J integral fracture toughness analy sis w as applied to compare in- fluence of modifier size with energy-absorption ability of elastic deformation and plastic deformation.Plas- tic deformation as main energy-absorption routes play s a major role in enhancing toughness of blends.AC R with size of 177.5 nm is found to be mostly effecti e, w hich is in accordance with the impact strength ac-