Co2＋-NaX催化膜的制备及其催化苯乙烯环氧化性能.pdfVIP

学兔兔 化 工 进 展 2010年第29卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·871· Co2+_NaX催化膜的制备及其催化苯乙烯环氧化性能 张 旭，李 芳，许茂东 (安徽工程科技学院生物化学工程系，安徽 芜湖 241000) 摘 要：采用水热法在Ⅱ一A12O3陶瓷管载体外表面原位合成x分子筛膜，再将其与Co(NO3)2．6H2O离子交换制备 催化膜，采用XRD、SEM、ICP等手段对催化膜进行表征，结果表明，催化膜牢固均匀地负载在载体的表面， 其厚度约20 gm，催化膜co 含量为8 40％。将其制备的催化接触型膜反应器用于苯乙烯氧气环氧化反应，并与 相同Co 含量的颗粒催化剂的性能进行比较，催化膜比颗粒催化剂具有更优的催化活性，其经7次循环使用， 活性和稳定性仍比较好，在反应过程中催化膜中的co 没有发生流失。 关键词：X型分子筛；催化膜；分子氧；苯乙烯；催化环氧化 中图分类号：TQ 241．2 1 文献标识码：A 文章编号：1000—6613(2010)05—0871—05 Preparation and catalytic performance of Co2+-NaX membrane for styrene epoxidation ZHANGXu，LI Fang，XUMaodong (Department ofBiochemical Engineering，Anhui University ofTechnology and Science，Wuhu 241000，Anhui，China) Abstract：Supported NaX zeolite membranes were successfully prepared on the outer surface of G【一alumina tube via in—situ hydrothermal synthesis followed by ion-exchange with Co(NO3)2·6H20 for preparing catalytic membranes．The catalytic membrane samples were characterized by XRD，SEM and ICE Results showed that the formation catalytic membranes was successful with an average thickness of 20 gm and the Co content of about 8．40％．The catalytic contact membrane reactor prepared with the prepared catalytic membrane was used for styrene epoxidation，which exhibited higher catalytic activity than that of particulate catalyst with same Co content．The catalytic membrane can be reused for seven times with high activity and stability，and no Co loss was detected in the reaction system． Key words：zeolite X：catalytic membrane；molecular oxygen； styrene；c