三甲基壳聚糖季铵盐水凝胶的制备及性能.pdfVIP

学兔兔 化 工 进 展 · 2266· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2011年第30卷第10期 三甲基壳聚糖季铵盐水凝胶的制备及性能 林佳福，辛梅华，李明春，祝二斌 (华侨大学材料科学与工程学院，环境友好功能材料教育部工程中心，福建 厦门 361021) 摘 要：采用反应活性强和交联条件温和的二乙烯基砜为交联剂，制备了Ⅳ，Ⅳ’Ⅳ_三甲基壳聚糖季铵盐水凝胶 (TMCG)并研究了TMCG的溶胀行为、水的状态和分布以及力学性能等。结果表明，TMCG在水中溶胀迅速， 平衡溶胀度达40倍，并且具有离子响应性；水分子在TMCG中以自由水、可冻结的结合水和非冻结的结合水三 种形式存在，其非冻结的结合水含量随交联剂浓度的增加而增大。TMCG具有良好的力学性能，拉伸强度达13．8 MPa，断裂伸长率达135-3％。 关键词：壳聚糖；季铵化；水凝胶；力学性能 中图分类号：O 636．1 文献标志码：A 文章编号：1000—6613(2011)10—2266—05 Preparation and properties of N,N,N-trimethyl chitosan quaternary ammonium hydrogel LINJiafu，XINMeihua，LIMingchun，ZHUErbin (College of Materials Science and Engineering，Huaqiao University，Engineering Research Center of Environment—Friendly FunctionalMaterials，Ministry ofEducation，Xiamen 361021，Fujian，China) Abstract：N,N,N-trimethyl chitosan quaternary ammoniumhydrogel(TMCG)was prepared in the mild condition by using reactive divinyl sulfone(DVS)as a cross—linking agent．The swelling behavior and mechanical properties of TMCG were investigated，together with the water state and distribution in swelling TMCG．The results show that TMCG is an ionic responsive hydrogel with fast swelling rate and high swelling ratio，the maximum equilibrium swelling ratio approaches to 40 times．TMCG has significant ionic responsiveness．Water molecules exist in the TMCG by three different forms of state as free water，freezing bound water，non—freezing bound water，and non—freezing bound water content increases with the increase of cross—linking agent．TMCG