十二水磷酸氢二钠的相变性能.pdfVIP

维普资讯 学兔兔 化 _T 进 展 · 900· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2008年第27卷第6期 十二水磷酸氢二钠的相变性能 盛青青，章学来，葛轶群 (上海海事大学蓄冷技术研究所，上海 200135) 摘 要：针对磷酸氢二钠的过冷进行研究，加入适量的成核剂降低其过冷度。实验结果表明，添加氧化铝对改 善磷酸氢二钠的过冷现象有很好的效果，相变温度保持在35~36℃，相变过程也可保持较长时间。同时，添 加一定量的羧甲基纤维素钠作为增稠剂，不仅可以改善蓄热体系的稳定性，而且对降低过冷度也有一定的 效果。 关键词：十二水磷酸氢二钠：过冷度；成核剂；增稠剂 中图分类号：TQ 126．3 5 文献标识码：A 文章编号：1000—66l3(2008)06—0900—04 Experimental study on phase change performance of disodium hydrogen phosphate dOdecahydrate SHENG Qingqing，ZHANGXuelai，GE Yiqun (Cold Storage Technology，Institute Shanghai Maritime University，Shanghai 200135，China) Abstract：The overcooling phenomena are very common in inorganic thermal storage materials．This paper mainly studied the overcooling phenomena of dibasic sodium phosphate．Adding an appropriate amount of anti—overcooling agent could reduce its overcooling．The experimental result indicated that， adding aluminum oxide had very good effect to reduce the overcooling of dibasic sodium phosphate， with the phase transform ation temperature kept at 35—36℃，and the phase change process could also be maintained for a long time．At the same time，adding some carboxymethylcellulose sodium as thickener not only could improve the stability of therm al storage system，but also could reduce the overcooling． Key words：disodium hydrogen phosphate dodecahydrate；overcooling；anti—overcooling；thickener 相变蓄热技术是利用相变材料在发生相变时需 kJ／kgI4’6-√J。但