沉淀pH值对TiO2-SiO2负载催化剂催化还原NO性能的影响.pdfVIP

学兔兔 化 工 进 展 2010年第29卷第2期 CHEMICAL INDUSTRY AND ENGINEERING PR0GRESS ·255· 沉淀pH值对TiO2．SiO2负载催化剂催化还原NO性能的影响 罗 河，黄 妍，童志权，罗 晶，夏 斌 (湘潭大学环境工程系，湖南 湘潭411105) 摘 要：采用共沉淀法，在不同pH值下制备了3种TiO2一SiO2(TS)复合氧化物，采用BET、XRD、NH3一TPD 和F丁IR等方法对样品进行了表征；并以3种Ts为载体，负载CuO、Cr203和CeO2活性组分，考察了不同Cu—Cr-Ce／TS 催化剂在140~220 CNH3选择性催化还原NO的性能。结果表明，以pH值10～11的Ts载体制备的Cu—Cr-Ce／TS 催化剂具有最优的低温活性，这是由于该载体具有较大的比表面积和更多弱酸中心，能吸附大量易于与NO反应 的氨。 关键词：TiO2一SiO2复合氧化物；共沉淀法；选择性催化还原；pH值 中图分类号：x 511 文献标识码：A 文章编号：1000—6613(2010)02—0255—05 Effect of precipitation pH values on the performance of TiO2-SiO2 supported catalyst for N0 reduction LUOHe，HUANG Yan，TONGZhiquan，LUOJing，XIABin (Department ofEnvironmental Engineering，Xiangtan University，Xiangtan 411105，Hunan，China) Abstract：TiO2一SiO2 mixed oxides(TS)were prepared under different pH values by CO—precipitation method and characterized by means of N2一physisortion，X—ray diffraction，temperature—programmed desorption and infrared spectroscopy．With these TS oxides as carrier and CuO，Cr203 and CeO2 as the active components，Cu-Cr-Ce／TS catalysts were prepared and their catalytic performance for the selective reduction of NO by NH3 was investigated between 140。C and 220。C．Results showed the Cu—Cr-Ce／TS catalyst，in which the TS was prepared under pH values between 10 and 1 1，appears to have the highest catalytic activity under lower temperature．This is due to the larger specific surface area and the more weak acid center of the TS support，through which a large number of NH3 molecules can be adsorbed as to react easily with NO． Key words：TiO2一SiO2 mixed oxid