Sulfur geochemistry of hydrothermal waters in Yellowstone National Park, Wyoming, USA. III. An anion-exchange resin technique for sampling and preservation of sulfoxyanions in natural waters 英文参考文献.docVIP

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Sulfur geochemistry of hydrothermal waters in Yellowstone National Park, Wyoming, USA. III. An anion-exchange resin technique for sampling and preservation of sulfoxyanions in natural waters 英文参考文献.doc

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SulfurgeochemistryofhydrothermalwatersinYellowstone NationalPark,Wyoming,USA.III.Ananion-exchangeresin techniqueforsamplingandpreservationofsulfoxyanionsin naturalwaters GregK.Druschel,a{MartinA.A.Schoonen,aD.KirkNordstrom,bJamesW.Ball,b YongXucandCoreyA.Cohnc Article Paper aDept.ofGeosciences,StateUniversityofNewYorkatStonyBrook,StonyBrook,NY11794. E-mail:Martin.Schoonen@SUNYSB.edu bU.S.GeologicalSurvey,3215MarineStreet,Boulder,CO80303 cDept.ofGeosciences,SUNYatStonyBrook,StonyBrook,NY11794 Received11thDecember2002,Accepted22ndMay2003 FirstpublishedasanAdvanceArticleontheweb4thJune2003 Asamplingprotocolfortheretention,extraction,andanalysisofsulfoxyanionsinhydrothermalwatershas beendevelopedinthelaboratoryandtestedatYellowstoneNationalParkandGreenLake,NY.Initial laboratorytestingoftheanion-exchangeresinBio-Rad2AG1-X8indicatedthattheresinwaswellsuitedfor thesampling,preservation,andextractionofsulfateandthiosulfate.Syntheticsolutionscontainingsulfateand thiosulfatewerepassedthroughAG1-X8resincolumnsandelutedwith1and3MKCl,respectively.Recovery rangedfrom89to100%.Comparisonofresultsforwatersamplescollectedfrom?vepoolsinYellowstone NationalParkbetweenon-siteICanalysis(U.S.GeologicalSurveymobilelab)andICanalysisofresin-stored sampleatSUNY-StonyBrookindicates96to100%agreementforthreepools(Cinder,Cistern,andan unnamedpoolnearCistern)and76and63%agreementfortwopools(SulfurDustandFryingPan).Attempts toextractpolythionatesfromtheAG1-X8resinweremadeusingHClsolutions,butwereunsuccessful. Bio-Rad2 AG2-X8,ananion-exchangeresinwithweakerbindingsitesthantheAG1-X8resin,isbettersuited forpolythionateextraction.SulfateandthiosulfateextractionwiththisresinhasbeenaccomplishedwithKCl solutionsof0.1and0.5M,respectively.Trithionateandtetrathionatecanbeextractedwith4MKCl.Higher polythionatescanbeextractedwith9Mhydrochloricacid.Polythionateconcentrationscanthenbedetermined directlyusingionchromatographicmethods,andlaboratoryresultsindicaterecoveryofupto90%for syntheticpolythionatesolutions