钨矿区砷污染土壤酶活性研究-有色金属科学与工程.doc

钨矿区砷污染与土壤微生物及酶活性相关性研究 周丹，赵永红，，张静 （江西理工大学资源与环境工程学院，江西 赣州 341000） 摘要： 关键词：钨矿砷污染土壤酶活性中图分类号X703.5 文献标码A 文章编号 The correlation between Soil enzyme activity , microbial community with content and chemical forms of As in the tungsten mine area Zhou Dan, Zhao Yong-hong, Wang Chun-hui , Zhang Jing （ Faculty of resource and environmental engineering, Jiang Xi University of Science and Technology, The Key Laboratory of Mining and Metallurgy Environmental Pollution Control, JiangXi, 341000.） Abstract：arsenic pollutionMicroflora composition and soil enzyme activity were analyzed at Tungsten mine area in Ganzhou by sampling. In the mining area，the concentrations of soil As were significantly higher than those in the non-mining area, in which Fe-Mn oxides of As were 35%~40% and exchangeable As were 9.8%~12%. While, Residual form dominated in the trailing sand, and exchangeable As were 16.6%. The microflora composition decreased obviously at polluted mine soil, and the susceptive order of three soil micro-organism to As was bacteria actinomycetes fungi. Enzyme activity at mine soil was lower than that at non-mine soil, by correlation analyzing, urease activity shows significant negative relation with soil As that was more sensitive indicators of As pollution at mine area. Therefore, the microflora composition and activity of soil enzyme microorganism could reflected the characteristics of heavy metal pollution characteristics, and the evolvement law of ecosystem function in polluted mine area at tungsten mine area. Keywords: tungsten mine area, arsenic pollution, soil enzyme activity, soil microorganism. 矿产资源开采过程中，伴生的有害金属元素通过搬运、扩散到地表后，在表生地球化学作用下产生严重的重金属污染，是目前矿山生态环境保护迫切需要解决的问题。江西赣州素有“钨都”之称，自1907年江西省大余县西华山钨矿伴生组分有锡、钼、铋、铜、锌、锑、锂、铌、硫、砷等通过迁移转化被生物，最终危害到人类的 分析矿区土壤砷污染现状，探讨矿区砷污染程度、形态与土壤微生物、酶活性之间的内在关系，为钨矿区土壤环境质量评价、矿区土地利用和生态环境修复提供科学依据。 1 采样矿区概况 采样矿区位于江西省崇义县辖区内，地理坐标：东经114°12′45″—114°14′56″，北纬25°37′45″—25°40′00面积15.212，区内为中低山地貌，.1 样品采集与处理 矿区地形为低山丘陵，因此采样以尾矿堆积区为起点，沿沟谷向下游，用蛇形布点法，在每个进行样，