化工原料中甲缩醛的顶空气相色谱_质谱联用测定方法研究.pdfVIP

2010 6 20 6 Chinese Journal ofHealth LaboratoryTechnology, Jun 2010; Vol20 N o6 1341 化工原料中甲缩醛的顶空气相色谱-质谱联用测定方法研究 张英, 蔡志斌, 刘丽 (, 518172) [] : - : , HP- 5 , 60! , 30m in,- : 0 g~ 200 g , 09997, 016mg/kg, 17% ~ 58% ( n = 6), 80% ~ 1045% : , [] 甲缩醛; 顶空气相色谱-质谱联用法;化工原料 + [] O6577 1 [] [] 1004- 8685(2010) 06- 1341- 03 Research on method for determination ofm ethylal in chemical raw materials by head spaceGC-MS ZH AN G Y ing, CA I Zh ibin, LI U L i ( Longgang Centre forD isease Control and Prevention, Shenzhen 518172, China) [Abstract] Objective:To establish amethod formethylal in the chem ical raw materials by head spaceGC- MSMethods: The head space tempraturewas 60! and equilibrium tmi ewas 30 m in, HP - 5 capillary column was selected for separating Head Space GC- M S, and finally detected by mass detectorResults: The good linear range of method was 0 g to 200 g ( r = 09997)with the correlation coeffivient of 09997, and the lmi it concentration in air was 016 mg/kg with the average relative standard deviation bewt een 17% ~ 58% ( n = 6), with average recoveries ranged from 80% to 1045% Conclusion: This method is sensitive, accurate and precise for rapid determ iantion ofmethylal from chemical raw materialsIt is suitable for deter m ining methylal in the chemical raw materials [ eywords] M ethylal; Head SpaceGC- MS; Chem ical raw materials [ 1, 2] ( ) ), , , 7609, ( 20! / 3 4! ) 08601 g/cm , 423! , ( 20! ) 40 kPa, , , 450 12 器与试剂 , ( Thermo F i