Mo-Si经烧结转变为MoSi2-SiC的过程.pdfVIP

维普资讯 学兔兔 第13卷第1期 粉末冶金材料科学与工程 2008年2月 、，01．13No．1 Materials Science and Engtneering of Powder M Feb．2O08 Mo．Si经烧结转变为MoSi2．SiC的过程 闫志巧，熊 翔，肖 鹏，陈 峰，黄伯云 (中南大学 粉末冶金国家重点实验室，长沙 410083) 摘 要：在C／SiC复合材料表面刷涂Mo．Si浆料，在l 430℃真空烧结。借助DSC分析研究Mo．Si反应的动力学 过程，通过XRD和SEM研究烧结产物的结构和形貌，并深入分析SiC的形成过程。结果表明： 温度低于Si熔 点时，Mo．Si反应以Si的扩散为控制步骤，反应速率缓慢，生成产物依次为Mo3Si和Mo5Si3等中间相，而在Si 熔点附近迅速转变为MoSi2；刷涂试样烧结后均生成多孔MoSi2．SiC，其内层为网络状结构MoSi2．SiC，表层为 SiC生长锥和晶须：随Si含量增加，MoSi2．SiC层致密度增加，SiC择优取向由(222)向(1l 1)转变。 关键词：动力学；扩散：硅化钼；MoSi2．SiC 中图分类号：TB 332 文献标识码：A 文章编号：1673．0224(2008)1．19．05 MoSi2-SiC formation process by sintering of Mo and Si mixture slurries YAN Zhi—qiao，XIONG Xiang，XIAO Peng，CHEN Feng，HUANG Bai-yun (State Key Laboratory ofPowder Metallurgy,Central South University,Changsha 410083，China) Abstract：Mo and Si mixture slurries welc brushed on C／SiC composites and sintered at 1 430℃ in vacuum to investigate the kinetics of Mo-Si reaction by DSC analysis and the composition and morphology ofthe products by XRD and SEM．The results show that，below Si melting point，the diffusion ofSi is the controlling step and the reaction rate is slow,the products serial includes intermediates Mo3Si，MosSi3 etc，however,nley quickly convert to MoSi2 near the Si melting point；after vacuum sintering at 1 430℃．the brushed Mo and Si mixture slurries all form porous MoSi2-SiC layer,whose inner is MoSi2-SiC networks and surface is SiC cones and