水溶液湿化学法可控制备超细镍粉.pdfVIP

学兔兔 第27卷第5期 粉末冶金技术 Vo1．27．No．5 2009年 10 Powder Metallurgy Technology 0ct．2009 水溶液湿化学法可控制备超细镍粉 翟爱霞 蔡雄辉 (武汉工业学院化学与环境工程学院，武汉 430023) 摘 要： 采用湿化学法制备不同形貌的超细镍粉。通过改变氯化镍的浓度、氢氧化钠的浓度、氯化镍与水合 肼和氢氧化钠的摩尔比、反应温度来控制超细镍粉的微观形貌；采用x衍射(XRD)和扫描电镜(SEM)对样品 进行表征。结果表明，可通过改变物质之间的摩尔比、反应物的浓度和反应温度实现对镍粉的形貌和尺寸调 控的目的。 关键词：镍粉；湿化学法；水溶液 Controlled preparation of ultra—fine nickel powders by wet-chemical method in aqueous solution Zhai Aixia，Cai Xionghui (College of Chemical and Environmental Engineering，Wuhan Polytechnic University，Wuhan 430023，China) Abstract：A wet-chemical method to synthesize ultra—fine nickel powders with different morphologies and sizes was presented．The well—defined uhra—fine nickel powders were prepared by changing the concentration of aqueous solution of nickel salt and sodium byoxide，or by changing the mole ratio between reactants and the reaction temperature． The resulting products were characterized by X—ray diffraction(XRD)and scanning electron microscopy(SEM)．It is found that the mole ratio between reactants，the concentration of reactants and reaetion temperature have much effect on the nlOl phologies and sizes of nickel powders，and it is concluded that the nickel powders with different morphologies can he prepared by adjusting them． Key words：nickel powders；wet-chemical method；aqueous solution - 由于超细镍粉在导电浆料、可充电电池、催化 学法一般是在碱性条件下用水合肼还原镍盐的水溶 剂、光学电子学、磁性存储材料等方面的工业应