钨骨架湿氢烧结工艺研究.pdfVIP

学兔兔 第13卷第6期 粉末冶金材料科学与工程 2008年12月 、，01．13 NO．6 Materials Science and Engineering of Powder Metallurgy Dec．2008 钨骨架湿氢烧结工艺研究 吴化波，王志法，刘金文，阮 涛 (中南大学 材料科学与工程学院，长沙 410083) 摘 要：为了降低钨骨架的烧结温度和提高钨铜复合材料的性能，采用湿氢烧结工艺制备钨骨架，对湿氢烧结一 熔渗法制备的w—l5Cu钨铜材料性能进行研究，并对钨的湿氢烧结机理进行探讨。采用扫描电镜(SEM)和X射线 衍射仪(XRD)对钨骨架和钨铜复合材料的组织与成分进行观察与分析，并测定材料的密度、气密性、热导率和热 膨胀系数(CTE)。结果表明：在1 450℃下湿氢烧结2 h，钨骨架发生较明显的烧结收缩和致密化 用该钨骨架制 备的钨铜材料的各项性能均达到热沉材料的要求。湿氢烧结机理主要是在湿氢条件下，通过反复进行的氧化与还 原使金属粉末表面形成激活能较低的新生态原子，从而使烧结温度降低。 关键词：钨铜复合材料；湿氢烧结：钨骨架；熔渗 中图分类号：TG 146．4 Il 文献标识码：A 文章编号：1673．0224(2008)6．365—04 Research of wet hydrogen sintering of W-skeleton WU Hua·bo，WANG Zhi—fa，LIU Jin—wen，RUAN Tao (School ofMaterials Science and Engineering，Central South University,Changsha 410083，China) Abstract：In order for decreasing W-skeleton’S sintering temperature and improving the properties of W-Cu composite． the W-skeleton was prepared at first with W-powders of 2．4．5．5 and 8 gm in diameter respectively and sintered in wet-hydrogen at 1 450 ℃ for 2 h．then W-1 5Cu composite material was prepared by infiltrating Cu into the sintered W-skeleton at l 350℃，finally the microstructure，composition，physical and mechanical properties were investigated by using SEM，XRD，etc，for both W-skeleton and W．1 5Cu composite materia1．The results show that，the W-skeleton prepared with d 2．4 gm W-powders exibites the best relative density(68．78％)and heighest bending strength(134．453 MPa)，the W-1 5 composites possess with ideal physical and mechanical properties，such as relative density 98．34％，