第六章 杂脍磁场中的原子.pptVIP

原 子 物 理 学 三、讨论 借助格罗春图计算波数的改变： mj 2 1 0 -1 -2 mj2g2 2 1 0 -1 -2 mj1g1 1 0 -1 （mj2g2 - mj1g1）= 0 0 0 -1 -1 -1 1 1 1 6.4 塞曼效应 对应九种跃迁，三条谱线 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. ? ? ? ?0 L ?0 1D2 1P1 6438 无磁场 有磁场 Cd6438?的正常塞曼效应跃迁图 mj mjg -1 -2 -1 -2 210 210 -1 -1 10 10 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 3.反常塞曼效应 对于具有双重或多重结构的光谱线在磁场中的分裂情况 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 例2 讨论Na双线： ， 在外场中的分裂 解： ， ， ， ， ， ， Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 2P1/2 2S1/2 mj 1/2 -1/2 mj2g2 1/3 -1/3 mj1g1 1 -1 （ mj2g2 - mj1g1 ） -2/3 2/3 -4/3 4/3 借助格罗春图计算波数的改变： 6.4 塞曼效应 分为4条，分裂谱线与原谱线波数差： Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 2P3/2 2S1/2 mj 3/2 1/2 -1/2 -3/2 mj2g2 6/3 2/3 -2/3 -6/3 mj1g1 1 -1 -1/3 1/3 -5/3 -3/3 3/3 5/3 6.4 塞曼效应 分为6条，分裂谱线与原谱线波数差： Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 3S 3P 不考虑自旋 考虑自旋 2S1/2 2P1/2 2P3/2 1/2 1/3 -1/2 -1/3 1/2 1 -1/2 -1 mjg -1/2 -2/3 mj 3/2 6/3 1/2 2/3 -3/2 -6/3 在磁场中 ?? ?? ??? ??? 5896 5890 5896 5890 5893 Na原子5890埃和5896埃双线的塞曼效应 2 4/3 2/3 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004