金属负载二氧化钛的制备及其对苯酚-环境工程学报.doc

复合金属氧化物的制备及其光催化性能研究 李贞玉1 刘美玲1 商希礼2 * 李长海2 （1. 长春工业大学化学院长春 130012）XRD )、X射线光电子能谱 ( XPS ) 和透射电镜 ( TEM ) 等手段对材料的晶体结构、元素和结构形貌 X703 文献标识码 A 文章编号 1673-9108(2016)03-0000-00 The preparation of complex metal oxides and the study on photocatalytic performance Li Zhenyu 1 Liu Meiling 1 Shang Xili 2* Li Changhai 1,2 (1. School of Chemical Engineering，Changchun University of Technology，Changchun 130012，China; 2. Department of Chemical Engineering，Binzhou University，Binzhou 256603，China;) Abstract A series of Ti-based complex metal oxides ( FeTiOx、FeAlTiOx and CuMgAlTiOx ) were synthesized by sol-gel method. The physicproperties of different catalysts were studied by X-ray diffraction ( XRD )、X-ray photoelectron spectroscopy ( XPS ) and transsmision electron microscope ( TEM )he photocatalytic degradation performance for Rhodamine B ( RhB ) was also investigated. Moreover, the effects of light source type, catalyst dosage and reaction time on the degradation reaction were systematically studied in the experiment. The results showed that complex metal oxides are better photocatalysts than pure TiO2. Among these complex metal oxides, FeAlTiOx has the best photocatalytic behavior, and the removal rate of RhB could reach up to 97.5﹪. Key wordscomplex metal oxide; photocatalysis; rhodamine B; degradation 随着工业化的发展，工业废水的排放量日益增加，这导致了严重的环境问题。传统的水处理方法有物理法、化学法、物理化学法[1] 、生物法等，例如化学氧化等方法，易引起二次污染传统的处理方法已越来越难以满足生产和环保的要求。因此，有机污染物是。TiO2光催化方法因具有高活性、无毒、相对稳定和强氧化能力等优点[7-9] 成为最具潜力的氧化术TiO2光催化剂存在光生电子空穴复合可见光利用率低因此，必须TiO2进行改性。金属掺杂与半导体复合是拓宽TO2可; 吉林省重点科技攻关项目(20130206069SF); 山东省自然基金项目(2015BSB01162); 山东省重点研发计划项目(2015GGX104012); 滨州市科技发展计划项目(2013ZC1602) 作者简介：李贞玉 (1974— ) ，女，博士，副教授，研究方向为污水处理工程。E-mail：cclzy2001@163.com E-mail：xilishang@126.com见光响应的有效途径之一TiO2进行单一元素掺杂，M. Jing等[11]人采用水热法制备了Fe掺杂TiO2光催化材料，在可见光下降解MB 3h 后，其降解率达到82﹪。近几年对共掺杂TiO2展开了研究。多金属共掺杂可以产生更多的掺杂能级和捕获中心，共掺杂对光催化起到的协同作用往往高于单一元素掺杂所起到的作用。沈良[6] 用制备的Fe、Mn、Cu1.1 试剂与仪器 钛酸丁酯、硝酸铁、硝酸铜、硝酸镁、硝酸铝、乙醇均为分析纯，二氧化钛（秦皇岛市太极环纳米制品有限公司）、罗