磁性纳米颗粒负载钯催化剂对Heck反应的催化活性_沈彬.pdfVIP

28 6 　　　 2007 6 Vol.28 No.6 ChineseJournal of Catalysis June 2007 :0253-9837(2007)06-0509-05 :509～513 Heck 1 1 1 2 沈　彬, 　李　游, 　王志飞, 　何农跃 (1 东南大学化学化工学院, 江苏南京211189;2 东南大学生物电子国家重点实验室, 江苏南京210096) : C/(Au @Fe), , 、X , Heck ., 300 nm, 12 nm , .Heck , 4 h, 95%.10 (88%).Heck , . , . :;;;;;;Heck : 643　　　:A Catalytic Activity of Palladium Supported on Magnetic Nanoparticles for Heck Reaction 1 ＊ 1 1 2 SHEN Bin , LI You , WANG Zhifei , HE Nongyue (1 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu, China; 2 State Key La oratory of Bioelectronics, Southeast University, Nanj ing 210096, Jiangsu, China) Abstract:Carbon-enclosed magnetic nanoparticles synthesized by the hydrothermal method were used as a sup- port for thepalladium nanoparticle catalyst.The catalyst samples were characterized by transmission electron mi- croscopy, X-ray photoelectron spectroscopy, and a vibration sample magnetometer.Its catalytic activity for the Heck coupling reaction was measured.The results showed that the mean catalyst particle size was 300 nm, the surface was covered with a layer of palladium particles (12 nm), and the catalyst was of superparamagnetic property .In the Heck reaction of iodobenzene and acrylic acid catalyzed by the catalyst, high iodobenzene con- version (more than 95%)could beobtained under the base conditions of both CH C Na and NEt after 4 h. 3 3 The iodobenzene conversion over the catalyst was about 88%after 10 recycles, and the catalyst could b