钒氧化物一维纳米材料的构筑与电输运性能_高倩.pdfVIP

第5卷 第4期 2010 年 4 月 中国科技论文在线 Sciencepaper Online 323 钒氧化物一维纳米材料的构筑与电输运性能 高 倩，麦立强，徐 林，顾彦辉，胡 彬，赵云龙，韩久慧 （武汉理工大学材料复合新技术国家重点实验室，材料科学与工程学院，武汉 430070 ） 摘 要：钒氧化物一维纳米材料因其新颖的结构和独特的电输运等特性，在纳电子和锂离子电池等领域受到广泛的关 注和重视。基于国内外最新研究进展及本课题组的研究工作，综述了钒氧化物一维纳米材料的制备技术和电输运性能 研究。首先介绍了Mo掺杂VO 纳米线阵列的形成机理及其半导体-金属相变特性；然后介绍了AgVO -PPy 同轴纳米电 2 3 缆和单根NH V O 纳米带器件的构筑与电输运特性。最后指出对单根钒氧化物一维纳米材料及其阵列器件的性能研究 4 3 8 是更深入探索此类材料的有效途径及发展方向。 关键词：一维纳米材料；钒氧化物；构筑；电输运性能 中图分类号：O611.4 文献标志码：A 文章编号：1673－7180(2010)04 －0323 －9 Construction and electrical transport properties of one-dimensional vanadium oxide nanomaterials Gao Qian ，Mai Liqiang ，Xu Lin ，Gu Yanhui ，Hu Bin ，Zhao Yunlong ，Han Jiuhui (State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China) Abstract: One-dimensional vanadium oxide nanomaterials have attracted great attention in the field of nanoelectronics, Li ion batteries and so on because of their novel structures and unique electrical transport and related properties. This paper reviews the current research on construction and electrical transport properties of one-dimensional vanadium oxide nanomaterials based on the latest literatures and our group’s work. First, the formation mechanism and semiconductor-metal phase transition of Mo-doped VO2 nanowire arrays are introduced. Then, the construction and electrical transport of AgVO -PPy coaxial nanocables and individual NH V O nanobelts are illustrated. It is pointed out that it is an effective way 3