Ce-TiO2光催化降解甲醛溶液的研究及应用前景.pdfVIP

学兔兔 新癯 隳 全国中文核心期刊 C e—Ti O2光催化降解甲醛溶液的 研究及应用前景 张浩 (安徽工业大学 建筑工程学院，安徽 马鞍山 243002) 摘要：以甲醛溶液的光催化降解为探针反应，评价了通过溶胶一凝胶技术制各的Ce—TiO 微粒对甲醛溶液的去除效果。采用x 射线衍射和激光粒度分析表征了Ce—TiO 的晶体结构与微晶尺寸。结果表明，掺杂ce可以促进TiO 由非正分锐钛矿相向锐钛矿相 和金红石相的转变，使晶体结晶完整，抑制载流子复合，从而达到Ce—TiO 在模拟自然条件可见光源下具有很好光催化降解甲醛溶 液的能力。 关键词：Ce—TiO ；光催化降解；甲醛溶液；环保 中图分类号：TQI34．1 1 文献标识码：A 文章编号：1001—702X(2010)11-0069—03 The study and appHcation prospect of photocatalytic degradation of formaldehyde solution by Ce—Tio2 zHANG Hao (School of Civil Engineering and Architecture，Anhui University of Technology，Maanshan 243002，Anhui，China) Abstract：By taking photocatalytic degradation of ~rmaldehyde solution as the probe reaction，the removal effect of Ce—Ti02 particle prepared with sol-gel method to formaldehyde solution was evaluated．The crystal pattern and crystalhte sizes of Ce-TiOz particle were characterized by mean of X—ray diffraction and laser particle size analyzer．Th e results show that Ce—Ti02 promotes the transformation from anatase phase of non—stoichiometric to anatase and rntile，making the particle crystal entire，restraining the recombination of charge carrier．Ce-TiO2 particle has very good photocatalytic activities under simulated natural conditions． Key words：Ce-TiO2；photocatal~ie degradation；formaldehyde solution；environmental protection 为了提高TiO 光催化过程的量子效率和对可见光能的 表1 主要试剂和仪器 利用率，必须对TiO 进行掺杂改性㈣。本文根据课题组长期 试剂 纯度 仪器 规格型号 从事掺杂Ti0 微粒光催化室内空气污染物的经验[31，采用溶 硝