三元共聚马来酰亚胺型聚羧酸系减水剂的制备与性能.pdfVIP

学兔兔 新鲤建蟓粉 中国科技核心期刊 ■●●■_ ■■■●● 元共聚马来酰亚胺型聚羧酸系 濂水剂的制备与性雒 李继新，王海阴，蒋锋，李志丹，赵远，张瑶 (沈阳工业大学 石油化工学院，辽宁 辽阳 111003) 摘要：以过硫酸铵(APS)为引发剂，N一聚乙二醇单甲醚一N 一氨基甲酰马来酰亚胺(MPNCM)、甲基丙烯磺酸钠(SMAS)和丙烯酸 (AA)为聚合单体，合成N一聚乙二醇单甲醚～N 一氨基甲酰马来酰亚胺一甲基丙烯磺酸钠一丙烯酸聚羧酸系减水剂(SP)。通过FI—IR和 H—NMR谱图对sP结构进行表征。以净浆流动度为指标，考察了MPNCM用量、SMAS用量、AA用量、引发剂用量、反应温度、反应 时间和投料方式对减水剂分散性的影响。结果表明：sP的最佳合成工艺为，将0．4％的APS和4 mol AA的水溶液，逐渐滴加到1 mol MPNCM和2 mol SMAS的水溶液中，在5O℃下反应6．0 h；以最佳反应条件合成的SP对水泥具有良好的适应性，并具有混凝土减水 率高、保坍性好、泌水率低和早强效果明显等特点。 关键词：N一聚乙二醇单甲醚一N，-氨基甲酰马来酰亚胺；甲基丙烯酸磺酸钠；丙烯酸；聚羧酸系减水剂 中图分类号：TU528．042．2 文献标识码：A 文章编号：1001—702X(2015)05—0033—04 Synthesis and property of maleimide-structural terpolymer polycarboxylate based superplasticizer LI Jixin，WANC Haiyue，殂ANG Fe ．Ll Zhidan，ZHA0 Yuan，ZHANG Yao (School of Petrochemical Engineering，Shenyang University of Technology，Liaoyang l 1 1003，Liaoning,China) Abstract：Polycarboxylate based superplasticizer(SP)was prepared from acrylic acid(AA)，sodium methylallyl sulfonate(SMAS) and N-Methoxypolyethylene glycols-N 一Carbamoylmaleimide(MPNCM)with ammonium persulphate(APS)a8 initiator． I e molecular structure of SP was characterized by FI-IR and H-NMR．Effects of the amount of MPNCM，SMAS and AA，the degree of initiator， polymerization temperature，polymerization time and feeding mode were investigated with initial fluidity as measurement index．The result shows thatthe optimal condition includes：the amount of MPNCM and SMAS is 1 tool and 2 tool，the amount of AA and radical initiator is 4 mol and 0．4％ according to the Inass are slowly dripped into reaction system．The reaction is carried