大单体结构对聚羧酸减水剂性能的影响.pdfVIP

学兔兔 中国科技核心期刊 新 建蟓 大单体结构对聚菝酸减水剂牲能的影嫡 张建锋，宋永良，王政伟，杨慧芬，李秋平 (浙江五龙新材股份有限公司，浙江 德清 313201) 摘要：以甲氧基聚乙二醇醚甲基丙烯酸酯(MPEG一1300MA)、丙烯醇聚乙二醇醚(APEG一1300)、甲基丙烯醇聚乙二醇醚 (MAPEG一2400)以及异戊烯醇聚乙二醇醚(IPEG一2400)4种不同结构的大单体为主体，辅助一定的可共聚单体在各自最佳工艺条 件下制备了4种聚羧酸减水剂。对合成的4种减水剂进行了适应性试验，并按GB 8076--2008《混凝土外加剂》测试减水剂的物化 性能和混凝土应用性能。测试结果表明，4种减水剂性能有一定的差异，但在混凝土应用中复配使用，可以做到性能互补。 关键词：大单体结构；聚羧酸减水剂；性能 中图分类号：TU528．042．2 文献标识码：A 文章编号：1001—702X(2014)04—0068—04 The influence of macromer structure on the performance of polycarboxylate superplasticizers ZHANG Jianfeng，SONG·Yongliang，WANG Zhengwei，YANG Huifen，LI Qiuping (Zhejiang Wulong New Materials Co．Ltd．，Deqing 313201，Zhoiang，China) Abstract：The compatibility of four kinds of polyearboxylate superplastieizers which were respectively synthesized with methoxy polyethylene glycol methacrylate(MPEG一1300MA)，allyl alcohol polyethylene ether(APEG-1300)，methallyl alcohol polyethy— lene ether(MAPEG一2400)and isoamylene alcohol polyethylene ether(IPEG-2400)adding with some eopolymerizable monomem at optimum proportion was tested eontrastively using mortar method．At the t~：qme time，the physicochemical properties and performance of concrete of four kinds of polyearboxylate superplastieizers were tested according to Chinese standard of GB 8076--2008”con— crete admixture”．The test results substantiate that there fire some distinctions among the performance of the four kinds of polyear- boxylate superplastieizers．But the polycarboxylate superplastieizers compounded were applied in the processes of concrete engineer— ing，the performances could be complementary． Key words：macromer structure：polyearboxylate superpl