端烯基双尾聚氧乙烯醚聚羧酸减水剂的合成及性能研究.pdfVIP

学兔兔 中国科技核心期刊 斩 建巍 撕 端烯基双尾聚氧乙烯醚聚菝酸减水剂的 ’ 合成及性能研究 黄文明，陈明中，魏运权 (湖北恒利建材科技有限公司，湖北荆州 434000) 摘要：以端烯基双尾聚氧乙烯醚为原料合成一种端烯基双尾聚氧乙烯醚聚羧酸减水剂。研究了单体摩尔比、引发剂用量、反应 时间、反应温度、大单体分子质量对合成减水剂的水泥净浆流动度的影响，得到最佳合成工艺条件：通过红外光谱、凝胶色谱表征对 减水剂进行分子结构分析；研究不同减水剂掺量对水泥净浆流动度的影响，并与常用的醚类、酯类聚羧酸盐减水剂进行性能对比。结 果表明，当减水剂掺量为O．28％时，减水率为36．8％，对水泥的适应性较好。 关键词：端烯基烷双尾聚氧乙烯醚；聚羧酸减水剂；减水率 中图分类号：TU528．042．2 文献标识码：A 文章编号：1001—702X(2015)03-0038-05 Synthes~ and properties of bis tail end dilute polyoxyethylenated polycarboxylate superplasticizer HUANG Wenming，CHEN Mingzhong，WEl Yunquan (Hubei Hengli Construction Material Technology Co．Ltd．，Jingzhou 434000，Hubei，China) Abstract：A kind of polycarboxylate water reducer was synthesized by polyoxyethylene ether．The influence of molar ratio of monomer，initiator amount，reaction time，reaction temperature and different molecule weiight on the cement paste fluidity of the water reducerWSS studied．The synthetic processparameters were optimized．The molecular structure was characterized by infrared spectroscopy and GPC．The influence on the fluidity of cement was researched by using different dosage．Its performances were compared with normal ether type and ester type polyearboxylate water reducer．The results showed that the water reducer has good adaptability with cement and water reduction is up to 36．8％，when its amount is 0．28％． Key words：polyoxyethylene ether，polycarboxylate water reducer，water reducing ratio 0 引 言 酸减水剂进行红外光谱结构表征及性能测试。 1试 验 随着建筑业的快速发展，对